Directly grown Te nanowire electrodes and soft plasma etching for high-performance MoTe2 field-effect transistors
Source abstract
Abstract
Abstract Contact tailoring for two-dimensional (2D) transition metal dichalcogenides (TMDs) to achieve high-performance devices remains a challenge. Fermi-level pinning at 2D TMD–metal contacts leads to a Schottky barrier for contacts. In addition, when there are no dangling bonds between 2D TMDs and contacts, the contact resistance increases. In this study, Te nanowire (NW) contacts were employed for a MoTe2 p-channel of enhancement mode field-effect transistor (FET). The Te NWs were directly grown on 2D MoTe2 film by metal–organic chemical vapor deposition and selectively etched by a soft plasma etching technique for contact isolation. Using t-Te NW contacts on three-atomic-layer MoTe2, a highly effective field-effect mobility of 543.9 cm2/Vs, as well as ohmic contacts and atomic hybridization, was achieved. These results of t-Te NW electrodes provide a novel device structure for p-type 2D TMD transistors with excellent performances. Further, they offer a practical guideline for wafer-scale 2D TMD-based high-performance electronics and optoelectronics.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: 2D Materials and Applications · Nanowire Synthesis and Applications · MXene and MAX Phase Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (44)
Show source-provided references
1. Optical Properties and Band Gap of Single- and Few-Layer MoTe2 Crystals10.1021/nl502557g ↗
2. Indirect-to-Direct Band Gap Crossover in Few-Layer MoTe210.1021/nl5045007 ↗
3. Two-dimensional semiconductors with possible high room temperature mobility10.1007/s12274-014-0532-x ↗
4. Bandgap opening in few-layered monoclinic MoTe210.1038/nphys3314 ↗
5. Song · Nano Lett. · 2016 · 16 · 18810.1021/acs.nanolett.5b03481 ↗
6. Room Temperature Semiconductor-Metal Transition of MoTe2 Thin Films Engineered by Strain10.1038/ncomms5214 ↗
7. Phase-Engineered Synthesis of Centimeter-Scale 1T′- and 2H-Molybdenum Ditelluride Thin Films10.1021/acsnano.5b02511 ↗
8. Chemical Vapor Deposition Growth of Few-Layer MoTe2 in the 2H, 1T′, and 1T Phases: Tunable Properties of MoTe2 Films10.1021/acsnano.6b07499 ↗
9. Wafer‐Scale Epitaxial 1T′, 1T′–2H Mixed, and 2H Phases MoTe2 Thin Films Grown by Metal–Organic Chemical Vapor Deposition10.1002/admi.201800439 ↗
10. Charge Mediated Reversible Metal-Insulator Transition in Monolayer MoTe2 and WxMo1–xTe2 Alloy10.1021/acsnano.6b00148 ↗
11. Coplanar semiconductor–metal circuitry defined on few-layer MoTe2 via polymorphic heteroepitaxy10.1038/nnano.2017.161 ↗
12. van der Waals Epitaxy of High-Mobility Polymorphic Structure of Mo6Te6 Nanoplates/MoTe2 Atomic Layers with Low Schottky Barrier Height10.1021/acsnano.8b07720 ↗
13. Phase-Controlled Growth of One-Dimensional Mo6Te6 Nanowires and Two-Dimensional MoTe2 Ultrathin Films Heterostructures10.1021/acs.nanolett.7b03058 ↗
14. Electrical metal contacts to atomically thin 2H-phase MoTe2 grown by metal–organic chemical vapor deposition10.1016/j.cap.2018.04.001 ↗
15. Contact Engineering High-Performance n-Type MoTe2 Transistors10.1021/acs.nanolett.9b02497 ↗
16. Ohmic Contacts to 2D Semiconductors through van der Waals Bonding10.1002/aelm.201500405 ↗
17. Phase patterning for ohmic homojunction contact in MoTe210.1126/science.aab3175 ↗
18. Electrical contacts to two-dimensional semiconductors10.1038/nmat4452 ↗
19. X-ray photoelectron spectroscopy study of MoTe2 single crystals and thin films10.1016/S0169-4332(03)00697-4 ↗
20. Dislocation-free Stranski-Krastanow growth of Ge on Si(100)10.1103/PhysRevLett.64.1943 ↗
21. Fast High-Responsivity Few-Layer MoTe2 Photodetectors10.1002/adom.201600290 ↗
22. Strong Enhancement of Raman Scattering from a Bulk-Inactive Vibrational Mode in Few-Layer MoTe210.1021/nn5007607 ↗
23. Review of inductively coupled plasmas: Nano-applications and bistable hysteresis physics10.1063/1.5012001 ↗
24. Supercritical fluid electrodeposition, structural and electrical characterisation of tellurium nanowires10.1039/C7RA07092F ↗
25. High-pressure phases of crystalline tellurium: A combined Raman and ab initio study10.1103/PhysRevB.86.064103 ↗
26. Raman Spectra and Lattice Dynamics of Tellurium10.1103/PhysRevB.4.356 ↗
27. Site-specific nucleation and controlled growth of a vertical tellurium nanowire array for high performance field emitters10.1088/0957-4484/24/18/185705 ↗
28. J.–W. Liu, J. Xu, W. Hu, J.-L. Yang, S.–H. Yu, Systematic Synthesis of Tellurium Nanostructures and Their Optical Properties: From Nanoparticles to Nanorods, Nanowires, and Nanotubes, ChemNanoMat 2 (2016) 167–170.10.1002/cnma.201500206 ↗
29. Synthesis of Atomically Thin Transition Metal Ditelluride Films by Rapid Chemical Transformation in Solution Phase10.1021/acs.chemmater.8b00684 ↗
30. Electrical Transport Properties of Single-Layer WS210.1021/nn502362b ↗
31. Far-infrared investigation of ternary Ge–Se–Sb and quaternary Ge–Se–Sb–Te chalcogenide glasses10.1016/j.jnoncrysol.2013.04.065 ↗
32. Dependence of structural cross-linking, system energy and transition temperature on coordination number for Sm doped GST10.1016/j.rinp.2019.102276 ↗
33. Overview of atomic layer etching in the semiconductor industry10.1116/1.4913379 ↗
34. Universal energy dependence of physical and ion-enhanced chemical etch yields at low ion energy10.1063/1.102336 ↗
35. Theory of Sputtering. I. Sputtering Yield of Amorphous and Polycrystalline Targets10.1103/PhysRev.184.383 ↗
36. Atomic Layer Etching: Rethinking the Art of Etch10.1021/acs.jpclett.8b00997 ↗
37. Electrical and Optical Characteristics of Two-Dimensional MoS2 Film Grown by Metal-Organic Chemical Vapor Deposition10.1166/jnn.2020.17490 ↗
38. Reconfigurable Complementary Monolayer MoTe2 Field-Effect Transistors for Integrated Circuits10.1021/acsnano.7b01306 ↗
39. Fermi Level Pinning at Electrical Metal Contacts of Monolayer Molybdenum Dichalcogenides10.1021/acsnano.6b07159 ↗
40. One-Dimensional Electrical Contact to a Two-Dimensional Material10.1126/science.1244358 ↗
41. MOCVD of C-oriented Bi2Te3 Films on SiO2 Substrates using Triethyl Bismuth and Di-tertiarybutyl Tellurium10.1002/cvde.201207012 ↗
42. Low-temperature growth of layered molybdenum disulphide with controlled clusters10.1038/srep21854 ↗
43. Floating probe for electron temperature and ion density measurement applicable to processing plasmas
44. Discharge mode transition and hysteresis in inductively coupled plasma10.1063/1.4809925 ↗