journal article·2020-09

Highly efficient photocatalytic hydrogen evolution driven by adjustable bimetal CuNi derived hexagonal Ni(OH)2

Lingjiao Li, Jing Xu, Binyi Su

Publisher page

Abstract

Abstract In the field of photocatalysis, most of the photocatalysts are semiconductors. Recent years, there have been many photocatalytic systems related to non-semiconductor catalysts. In this paper, a photocatalytic hydrogen evolution system of hexagonal Ni(OH)2 derived from CuNi bimetal is obtained by classical hydrothermal method. The derived hexagonal Ni(OH)2 can promote the separation of photogenerated electron-hole pairs and greatly improve the effect of photocatalytic hydrogen evolution. The electron-hole pair comes from the surface plasmon resonance (SPR) effect of Cu from CuNi composite. It is worth noting that photoluminescence spectra and photoelectrochemical experiments have confirmed that the CuNi-5 complex can effectively improve space charge separation. The results of linear scanning voltammetry show that the material has high current response characteristics. This system gives a practical solution for planning and synthesizing non-semiconductor catalysts with high photocatalytic activity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced Photocatalysis Techniques · Copper-based nanomaterials and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Redox shuttle mechanism enhances photocatalytic H2 generation on Ni-decorated CdS nanorods10.1038/nmat4049 ↗
2. Carbon quantum dots/hydrogenated TiO2 nanobelt heterostructures and their broad spectrum photocatalytic properties under UV, visible, and nearinfrared irradiation10.1016/j.nanoen.2014.10.025 ↗
3. Engineering the performance of heterogeneous WO3/fullerene@Ni3B/Ni(OH)2 Photocatalysts for Hydrogen Generation10.1016/j.ijhydene.2019.06.148 ↗
4. Ni-Mo Nanocatalysts on N-Doped Graphite Nanotubes for Highly Efficient Electrochemical Hydrogen Evolution in Acid10.1021/acsnano.6b06259 ↗
5. Ternary FexCo1–xP nanowire array as a robust hydrogen evolution reaction electrocatalyst with Pt-like activity: experimental and theoretical insight10.1021/acs.nanolett.6b03332 ↗
6. Computational high-throughput screening of electrocatalytic materials for hydrogen evolution10.1038/nmat1752 ↗
7. Photoinduced formation of Cu@Cu2O@C plasmonic nanostructures with efficient interfacial charge transfer for hydrogen evolution10.1039/C9TA05846J ↗
8. Detailed balance limit of efficiency of p-n junction solar cells10.1063/1.1736034 ↗
9. Dependence of photocatalytic activities upon the structures of Au/Pd bimetallic nanoparticles immobilized on TiO2 surface10.1016/j.apcatb.2009.11.015 ↗
10. Synergistic effect of g-C3N4, Ni(OH)2 and halloysite in nanocomposite photocatalyst on efficient photocatalytic hydrogen generation10.1016/j.renene.2019.01.103 ↗
11. Synergetic effect of Ni(OH)2 cocatalyst and CNT for high hydrogen generation on CdS quantum dot sensitized TiO2 photocatalyst10.1016/j.apcatb.2016.12.008 ↗
12. Interface engineering: The Ni(OH)2/MoS2 heterostructure for highly efficient alkaline hydrogen evolution10.1016/j.nanoen.2017.05.011 ↗
13. Fabrication of a non-semiconductor photocatalytic system using dendrite-like plasmonic CuNi bimetal combined with reduced graphene oxide nanosheet for near-infrared photocatalytic H2 evolution10.1039/C7TA06625B ↗
14. Aqueous Solution Synthesis of Pt–M (M = Fe Co, Ni) Bimetallic Nanoparticles and Their Catalysis for the Hydrolytic Dehydrogenation of Ammonia Borane10.1021/am502335j ↗
15. CuNi Dendritic Material: Synthesis, Mechanism Discussion, and Application as Glucose Sensor10.1021/cm070638a ↗
16. Incorporation of RuO2 into charcoal-derived carbon with controllable microporosity by CO2 activation for high-performance supercapacitor10.1016/j.carbon.2017.06.085 ↗
17. Stable and improved visible-light photocatalytic hydrogen evolution using copper(ii)–organic frameworks: engineering the crystal structures10.1039/C7TA00095B ↗
18. Copper nanowires: a substitute for noble metals to enhance Photocatalytic H2 Generation10.1021/acs.nanolett.5b00082 ↗
19. A floating sheet for efficient photocatalytic water splitting10.1002/aenm.201600510 ↗
20. Manipulating the hydrogen evolution pathway on composition-tunable CuNi nanoalloys10.1039/C6TA09169E ↗
21. Nanoporous surface alloys as highly active and durable oxygen reduction reaction electrocatalysts10.1039/C1EE02243A ↗
22. Ratio-Controlled Synthesis of CuNi Octahedra and Nanocubes with Enhanced Catalytic Activity10.1021/jacs.5b08289 ↗
23. Facile electrodeposition of Ni-Cu-P dendrite nanotube films with enhanced hydrogen evolution reaction activity and durability10.1021/acsami.8b12321 ↗
24. Universal Dependence of Hydrogen Oxidation and Evolution Reaction Activity of Platinum-Group Metals on Ph and Hydrogen Binding Energy
25. Photocatalytic hydrogen evolution by flexible graphene composites decorated with Ni(OH)2 nanoparticles10.1021/acs.jpcc.7b10375 ↗
26. Hierarchical TiO2/Ni(OH)2 composite fibers with enhanced photocatalytic CO2 reduction performance10.1039/C7TA10073F ↗
27. Enhanced photocatalytic H2-production activity of TiO2 by Ni(OH)2 cluster modification10.1021/jp111562d ↗
28. Architecture of high efficient zinc vacancy mediated Z–scheme photocatalyst from metal–organic frameworks10.1016/j.nanoen.2018.07.043 ↗
29. Plasmonic Cu nanoparticle on reduced graphene oxide nanosheet support: an efficient photocatalyst for improvement of near-infrared photocatalytic H2 evolution10.1016/j.apcatb.2017.11.076 ↗
30. The visible-light-assisted thermocatalytic methanation of CO2 over Ru/TiO(2–x)Nx10.1016/j.apcatb.2016.11.054 ↗
31. Synthesis of a plasmonic CuNi bimetal modified with carbon quantum dots as a non-semiconductor-driven photocatalyst for effective water splitting10.1016/j.jcat.2018.11.003 ↗
32. Design of plasmonic CuCo bimetal as a nonsemiconductor photocatalyst for synchronized hydrogen evolution and storage10.1016/j.apcatb.2018.10.020 ↗
33. Electrodeposition of magnetic, superhydrophobic, non-stick, two-phase Cu-Ni foam films and their enhanced performance for hydrogen evolution reaction in alkaline water media10.1039/C4NR03200D ↗
34. Boosting photocatalytic hydrogen evolution achieved by rationally designed/constructed carbon nitride with ternary cobalt phosphosulphide10.1016/j.jcis.2019.04.045 ↗
35. Enhanced hydrogen production from ammonia borane over CuNi alloy nanoparticles supported on TiO2 (B)/anatase mixed-phase nanofibers with high specific surface area10.1016/j.jallcom.2019.152431 ↗
36. Synergistic effect of g-C3N4, Ni(OH)2 and halloysite in nanocomposite photocatalyst on efficient photocatalytic hydrogen generation10.1016/j.renene.2019.01.103 ↗
37. Synergistic effect based NixCo1-x architected Zn0.75Cd0.25S nanocrystals: An ultrahigh and stable photocatalysts for hydrogen evolution from water splitting10.1016/j.apcatb.2017.10.010 ↗