Tunable ITO–metal plasmonic metamaterial channel for tailored sensing: A simulation-driven approach
Source abstract
Abstract
We present a transparent, conductive metamaterial channel formed by embedding a triangular lattice of Au, Ag, or Cu nanodisks inside an indium–tin–oxide (ITO) slab, enabling geometry-programmable resonant absorption from 400 to 1100 nm. Using finite-difference time-domain simulations with periodic in-plane boundaries, we map how five structural parameters—disk diameter d, disk thickness t, lattice constant a, ITO thickness tc, and vertical lattice placement h—govern localized surface plasmon resonances, linewidth, and peak amplitude. Across metals, increasing t primarily blue-shifts the resonance wavelength; increasing d red-shifts the dominant localized surface plasmon resonances; larger a narrows the resonance peak FWHM; thicker ITO red-shifts the peak; and moving the lattice along strongly modulates absorbance, revealing birefringence-like asymmetry for top-down illumination. Field maps confirm dual modal hot-spots. To connect tunability with device targets, we couple the solver to a derivative-free, black-box optimization code that inversely designs the metamaterial channel to match user-defined spectra. As a case study, we realize a dual-peak response (600 nm, 10 nm FWHM; 800 nm, 80 nm FWHM; peak A = 0.5) with feasible parameter sets for Au, Ag, and Cu. The metamaterial channel is compatible with nanofabrication procedures, and its conductive host permits future electro-optic biasing for dynamic tuning. This simulation-driven framework provides a compact route to spectrally programmable absorbers for refractive-index sensing, pixel-level color filtering, photodetection, and plasmon-enhanced optoelectronics.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Metamaterials and Metasurfaces Applications · Plasmonic and Surface Plasmon Research · Photonic Crystals and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
IST 1 , Lisbon,
Sapienza 2 , Roma,
IPFN 3 , Lisbon, and , Lisbon,
ISEG 3 , Lisbon, and , Lisbon,
INESC MN 4 , Lisbon,
References (60)
Show source-provided references
1. Plasmonic antennas with electric, magnetic, and electromagnetic hot spots based on Babinet’s principle10.1103/physrevapplied.13.054045 ↗
2. Modulation of surface response in a single plasmonic nanoresonator10.1126/sciadv.adn5227 ↗
3. Developments in localized surface plasmon resonance10.1007/s11468-024-02620-x ↗
4. Localized surface plasmon resonance of copper nanoparticles improves the performance of quasi-two-dimensional perovskite light-emitting diodes10.1016/j.dyepig.2021.109204 ↗
5. Fabrication of plasmonic indium tin oxide nanoparticles by means of a gas aggregation cluster source10.1021/acsomega.2c08070 ↗
6. Comparing silver and gold nanoislands’ surface plasmon resonance for bisacodyl and its metabolite quantification in human plasma10.1186/s13065-024-01157-8 ↗
7. Intensity-based single particle plasmon sensing10.1021/acs.nanolett.0c04702 ↗
8. Bound states in the continuum in a waveguide structure covered by a two-dimensional square array of gold nanodisks10.1103/physrevb.108.205425 ↗
9. Comparative assessment of surface lattice resonance characteristics in plasmonic titanium nitride and gold nanodisk arrays10.3390/solids6010008 ↗
10. Plasmonic nanotechnology for photothermal applications – An evaluation10.3762/bjnano.14.33 ↗
11. Strong exciton–plasmon coupling in MoS2 coupled with plasmonic lattice10.1021/acs.nanolett.5b04588 ↗
12. Metal–insulator–metal plasmonic absorbers: Influence of lattice10.1364/oe.22.030807 ↗
13. Tunable plasmonic metamaterial based on transparent conducting oxide10.1117/12.2037921 ↗
14. Ultrasensitive biosensing based on plasmonic nanostructures10.1117/12.2541278 ↗
15. Indium–tin–oxide nanostructures for plasmon-enhanced infrared spectroscopy: A numerical study10.3390/mi10040241 ↗
16. Pulsed current electrodeposition of gold nanostructures on ITO: Control of particle density and optical transmission10.1016/j.rio.2023.100471 ↗
17. Modulating mechanism of the LSPR and SERS in Ag/ITO film: Carrier density effect10.1021/acs.jpclett.1c01727 ↗
18. Electrically tunable plasmonic absorber based on Cu-ITO subwavelength grating on SOI at telecom wavelength10.1007/s11468-022-01658-z ↗
19. Ultrathin and electrically tunable metamaterial with nearly perfect absorption in mid-infrared10.3390/app9163358 ↗
20. Graphene-based tunable wideband metamaterial absorber with polarization insensitivity and wide incident angle10.3389/fphy.2020.00303 ↗
21. Highly sensitive THz refractive index sensor based on folded split-ring metamaterial graphene resonators10.1007/s11468-021-01512-8 ↗
22. Plasmon-enhanced light–matter interactions and applications10.1038/s41524-019-0184-1 ↗
23. A review of tunable photonics: Optically active materials and applications from visible to terahertz10.1016/j.isci.2022.104727 ↗
24. Photodetection with active optical antennas10.1126/science.1203056 ↗
25. Metal/semiconductor hybrid nanostructures for plasmon-enhanced applications10.1002/adma.201400203 ↗
26. Ultra-high-responsivity broadband detection of Si metal–semiconductor–metal Schottky photodetectors improved by ZnO nanorod arrays10.1021/nn203357e ↗
27. Plasmonic nanoresonators for high-resolution colour filtering and spectral imaging10.1038/ncomms1058 ↗
28. Highly selective color filters based on hybrid plasmonic–dielectric nanostructures10.1021/acsphotonics.1c01983 ↗
29. Indium-tin-oxide for high-performance electro-optic modulation10.48550/arXiv.2305.10639 ↗
30. Electrically tunable epsilon-near-zero (ENZ) metafilm absorbers10.1038/srep15754 ↗
31. Thermoplasmonics: Using metallic nanostructures as nano-sources of heat10.1002/lpor.201200003 ↗
32. Alternative plasmonic materials: Beyond gold and silver10.1002/adma.201205076 ↗
33. Low-loss plasmonic metamaterials10.1126/science.1198258 ↗
34. Photonic design principles for ultrahigh-efficiency photovoltaics10.1038/nmat3263 ↗
35. A clearer vision for in vivo imaging10.1038/86684 ↗
36. 1998
37. Ansys Inc, “Lumerical FDTD solutions,” https://www.lumerical.com/products/fdtd/ (2023) (accessed 23 May 2025).
38. Lide · 2003
39. Optical constants of the noble metals10.1103/physrevb.6.4370 ↗
40. 1997
41. Monitoring the electrochemical failure of indium tin oxide electrodes via operando ellipsometry complemented by electron microscopy and spectroscopy10.1021/acsami.3c17923 ↗
42. Ultrasensitive probing of plasmonic hot electron occupancies10.1038/s41467-022-34554-5 ↗
43. Ultrafast switching of tunable infrared plasmons in indium tin oxide nanorod arrays with large absolute amplitude10.1038/nphoton.2016.14 ↗
44. Plasmon-induced hot carrier science and technology10.1038/nnano.2014.311 ↗
45. Highly flexible touch screen panel fabricated with silver-inserted transparent ito triple-layer structures10.1039/c7ra13550e ↗
46. Near-infrared plasmon-induced hot electron extraction evidence in an indium tin oxide nanoparticle/monolayer molybdenum disulfide heterostructure10.1021/acs.jpclett.2c02358 ↗
47. Clear and transparent nanocrystals for infrared-responsive carrier transfer10.1038/s41467-018-08226-2 ↗
48. Mechanism for plasmon-generated solvated electrons10.1073/pnas.2217035120 ↗
49. Understanding the mechanism of plasmon-driven water splitting: hot electron injection and a near field enhancement effect10.1039/D1CP03509F ↗
50. Quantifying the ultimate limit of plasmonic near-field enhancement10.1038/s41467-024-53210-8 ↗
51. Plasmon localization and field enhancement in flexible metasurfaces10.1103/physrevapplied.22.064064 ↗
52. Deep learning-enabled gradient-based optimization of near-field enhancement in nano-plasmonic structures10.1063/5.0252572 ↗
53. Electrical detection of surface plasmon resonance phenomena by a photoelectronic device integrated with gold nanoparticle plasmon antenna10.1063/1.4792210 ↗
54. Electrical plasmon detection in graphene waveguides10.1103/physrevb.91.081402 ↗
55. Plasmonic nanopatch array for optical integrated circuit applications10.1038/srep03172 ↗
56. Plasmonic and conductive structures of TCO films with embedded Cu nanoparticles10.3390/ijms231911886 ↗
57. Forming ITO/Ag hole-array/ITO multilayers for near infrared transparent conducting electrodes and filters10.1149/2.0081910jss ↗
58. Plasmonic resonances in nanostructured transparent conducting oxide films10.1109/JSTQE.2013.2238611 ↗
59. Worst case complexity bounds for linesearch-type derivative-free algorithms10.1007/s10957-024-02519-x ↗
60. A. Brilli , A.Cristofari, G.Liuzzi, and S.Lucidi, “Complexity results and active-set identification of a derivative-free method for bound-constrained problems,” arXiv:2402.10801 [math.OC] (2024).