journal article·2021-05-01Open access

Ce-doped LaCoO3 film as a promising gas sensor for ethanol

Liang Wu, Xiang Shi, Huiling Du, Qunli An, Zhuo Li, Hang Xu, Hongpei Ran

AIP Advances· Volume 11· Issue 5

Abstract

With increasing exposure to ethanol in various scenarios, including hand sanitizers that combat bacteria and viruses, energy-efficient miniaturized sensors capable of detecting excessive concentrations of ethanol are required in the fields of disinfection and chemical storage. Modified perovskite-type oxides with ABO3 structures are particularly attractive because they can be appropriately modified and have been used in heterogeneous catalysis and gas sensors. In this study, we designed and manufactured a novel thin-film-type LaCeCoO3 gas sensor using lithography technology and precursor-solution doping. The samples exhibited morphologies that contain randomly oriented nanostructures and short rods; the particle size was observed to decrease with Ce-addition. Room-temperature gas-sensing characterization studies revealed high reproducibility for the detection of ethanol. La0.96Ce0.04CoO3 exhibited superior stability and sensitivity, with a high impedance, |Z|, of ∼120 kΩ and a Δ|Z| of up to 77%, with response and recovery times of 16 and 8 s, respectively. This study provides a rational method for the development of LaCeCoO3 as a semiconducting material for ethanol gas-sensing applications.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Analytical Chemistry and Sensors · Advanced Chemical Sensor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering, Xi’an University of Science and Technology , Xi’an 710054, China

References (40)

Show source-provided references
1. Breakthroughs in the design of novel carbon-based metal oxides nanocomposites for VOCs gas sensing10.3390/nano10081485 ↗
2. Detection of hazardous volatile organic compounds (VOCs) by metal oxide nanostructures-based gas sensors: A review10.1016/j.ceramint.2016.06.145 ↗
3. Alcohol and health: Standards of consumption, benefits and harm—A review10.17221/117/2018-CJFS ↗
4. Hazard identification of exhausts from gasoline-ethanol fuel blends using a multi-cellular human lung model10.1016/j.envres.2016.09.010 ↗
5. Fabrication, structure, and frequency-dependent electrical and dielectric properties of Sr-doped BaTiO3 ceramics10.1016/j.ceramint.2019.09.208 ↗
6. PGM-free CuO/LaCoO3 nanocomposites: New opportunities for TWC application10.1016/j.apcatb.2018.01.053 ↗
7. Fabrication of nanofibrous A- or B-sites substituted LaCoO3 perovskites with macroscopic structures and their catalytic applications10.1016/j.materresbull.2013.12.038 ↗
8. Structural investigation of LaCoO3 and LaCoCuO3 perovskite-type oxides and the effect of Cu on coke deposition in the partial oxidation of methane10.1016/j.apcatb.2012.01.009 ↗
9. Fabrication, characterization and n-propanol sensing properties of perovskite-type ZnSnO3 nanospheres based gas sensor10.1016/j.apsusc.2020.145335 ↗
10. Recent advances of lanthanum-based perovskite oxides for catalysis10.1021/acscatal.5b01667 ↗
11. Sulfur resistance of Ca-substituted LaCoO3 catalysts in CO oxidation10.1016/j.mcat.2019.02.020 ↗
12. Pseudo core-shell LaCoO3@MgO perovskite oxides for high performance methane catalytic oxidation10.1016/j.jre.2020.02.014 ↗
13. Humidity sensor applications based on mesopores LaCoO310.1007/s10854-019-02284-y ↗
14. LaCoO3-based sensors with high sensitivity to carbon monoxide10.1039/c5ra10521h ↗
15. CO sensitive nanocrystalline LaCoO3 perovskite sensor prepared by high energy ball milling10.1016/j.snb.2010.05.056 ↗
16. Characterization of LaCoO3 powders obtained by water-based sol–gel method with citric acid10.1016/j.jeurceramsoc.2007.02.161 ↗
17. Substrate-dependent structural and CO sensing properties of LaCoO3 epitaxial films10.1016/j.apsusc.2018.02.221 ↗
18. CO sensing mechanism of LaCoO310.1016/j.ssi.2015.01.015 ↗
19. CeO2-based mixed potential type acetone sensor using La1-xSrxCoO3 sensing electrode10.1016/j.snb.2018.04.160 ↗
20. Key processing of porous and fibrous LaCoO3 nanostructures for successful CO and propane sensing10.1016/j.ceramint.2018.05.192 ↗
21. Improvement of the gas sensing response of nanostructured LaCoO3 by the addition of Ag nanoparticles10.1016/j.snb.2017.02.045 ↗
22. Nanocrystalline LaCoO3 modified by Ag nanoparticles with improved sensitivity to H2S10.1016/j.snb.2019.126661 ↗
23. Thick films of In, Bi and Pd metal oxides impregnated in LaCoO3 perovskite as carbon monoxide sensor10.1016/j.snb.2004.09.008 ↗
24. Near room temperature CO sensing by mesoporous LaCoO3 nanowires functionalized with Pd nanodots10.1016/j.snb.2015.08.099 ↗
25. Design of porous p-type LaCoO3 nanofibers with remarkable response and selectivity to ethanol at low operating temperature10.1016/j.snb.2020.127670 ↗
26. Appl. Surf. Sci. · 2020 · 521 · 14646310.1016/j.apsusc.2020.146463 ↗
27. A DFT study of dissolved gas (C2H2, H2, CH4) detection in oil on CuO-modified BNNT10.1016/j.apsusc.2019.144030 ↗
28. Influence of Ce doping on catalytic oxidation of NO on LaCoO3 (011) surface: A DFT study10.1016/j.apsusc.2019.143866 ↗
29. Ethanol combustion over strontium- and cerium-doped LaCoO3 catalysts10.1016/j.apcatb.2006.12.006 ↗
30. Microstructure evolution and dielectric properties of Ce-doped SrBi4Ti4O15 ceramics synthesized via glycine-nitrate process10.2298/pac1804303d ↗
31. Nanoscale domains of ordered oxygen-vacancies in LaCoO3 films10.1016/j.apsusc.2017.06.315 ↗
32. Synergistic improvements in stability and performance of the double perovskite-type oxides La2−xSrxFeCoO6 for chemical looping steam methane reforming10.1016/j.apenergy.2017.04.049 ↗
33. Evidence of phase cooperation in the LaCoO3–CeO2–Co3O4 catalytic system in relation to activity in methane combustion10.1016/s0926-860x(01)00903-6 ↗
34. Ethanol gas sensor based on γ-Fe2O3 nanoparticles working at room temperature with high sensitivity10.1016/S1872-2040(18)61098-9 ↗
35. Fabrication of single crystalline WO3 nano-belts based photoelectric gas sensor for detection of high concentration ethanol gas at room temperature10.1016/j.sna.2020.111865 ↗
36. Preparation and characterization of a novel ethanol gas sensor based on FeYO3 microspheres by using orange peels as bio-templates10.1016/j.vacuum.2020.109359 ↗
37. Room-temperature self-powered ethanol sensor based on the piezo-surface coupling effect of heterostructured α-Fe2O3/ZnO nanowires10.1016/j.matlet.2015.12.106 ↗
38. Tungsten trioxide nanotubes with high sensitive and selective properties to acetone10.1016/j.snb.2013.12.078 ↗
39. Wearable carbon monoxide sensors based on hybrid graphene/ZnO nanocomposites10.1109/access.2020.2976841 ↗
40. One step synthesis of branched SnO2/ZnO heterostructures and their enhanced gas-sensing properties10.1016/j.snb.2018.10.138 ↗