journal article·2018-01Open access

Organic Semiconductors: Zigzag‐Elongated Fused π‐Electronic Core: A Molecular Design Strategy to Maximize Charge‐Carrier Mobility (Adv. Sci. 1/2018)

Akito Yamamoto, Yoshinori Murata, Chikahiko Mitsui, Hiroyuki Ishii, Masakazu Yamagishi, Masafumi Yano, Hiroyasu Sato, Akihito Yamano, Jun Takeya, Toshihiro Okamoto

Advanced Science· Volume 5· Issue 1

Abstract

In article number 1700317, Toshihiro Okamoto, Hiroyuki Ishii, and co-workers report chryseno[2,1-b:8,7-b′]dithiophene (ChDT) and its derivatives, which have zigzag-elongated fused π-cores and peculiar highest occupied molecular orbital (HOMO) configurations, as materials with conceptually new semiconducting π-cores. The ChDT π-core exhibits increasing structural stability in the bulk crystal phase and is unaffected by a variation of the transfer integral induced by the perpetual molecular motion of organic materials.
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Research context

OpenAlex topics: Conducting polymers and applications · Organic Electronics and Photovoltaics · Organic and Molecular Conductors Research

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Affiliations

Department of Advanced Materials Science Graduate School of Frontier Sciences The University of Tokyo 5‐1‐5 Kashiwanoha Kashiwa Chiba 277‐8561 Japan

Chemistry, Materials and Bioengineering Major Graduate School of Science and Engineering Kansai University 3‐3‐35 Yamate‐cho Suita Osaka 564‐8680 Japan

Division of Applied Physics Faculty of Pure and Applied Sciences University of Tsukuba 1‐1‐1 Tennodai Tsukuba Ibaraki 305‐8573 Japan

National Institute of Technology Toyama College 13 Hongo‐machi Toyama Toyama 939‐8630 Japan

Rigaku Corporation 3‐9‐12 Matsubara‐cho Akishima Tokyo 196‐8666 Japan

PRESTO Japan Science and Technology Agency (JST) 4‐1‐8 Honcho Kawaguchi Saitama 332‐0012 Japan

References

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