journal article·2023-04Open access

Recruiting Unicellular Algae for the Mass Production of Nanostructured Perovskites

Lucas Kuhrts, Lukas Helmbrecht, Willem L. Noorduin, Darius Pohl, Xiaoxiao Sun, Alexander Palatnik, Cornelia Wetzker, Anne Jantschke, Michael Schlierf, Igor Zlotnikov

Advanced Science· Volume 10· Issue 11

Abstract

Abstract Functional capacities of lead halide perovskites are strongly dependent on their morphology, crystallographic texture, and internal ultrastructure on the nano‐ and the meso‐scale. In the last decade, significant efforts are directed towards the development of novel synthesis routes that would overcome the morphological constraints provided by the physical and crystallographic properties of these materials. In contrast, various living organisms, such as unicellular algae, have the ability to mold biogenic crystals into a vast variety of intricate nano‐architectured shapes while keeping their single crystalline nature. Here, using the cell wall of the dinoflagellate L. granifera as a model, sustainably harvested biogenic calcite is successfully transformed into nano‐structured perovskites. Three variants of lead halide perovskites CH3NH3PbX3 are generated with X = Cl−, Br− and I−; exhibiting emission peak‐wavelength ranging from blue, to green, to near‐infrared, respectively. The approach can be used for the mass production of nano‐architectured perovskites with desired morphological, textural and, consequently, physical properties exploiting the numerous templates provided by calcite forming unicellular organisms.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Electrocatalysts for Energy Conversion · Advanced Nanomaterials in Catalysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

B CUBE – Center for Molecular Bioengineering Dresden University of Technology Tatzberg 41 01307 Dresden Germany

AMOLF Science Park 104 Amsterdam 1098 XG The Netherlands

Van ‘t Hoff Institute for Molecular Sciences University of Amsterdam Amsterdam 1090 GD The Netherlands

Dresden Center for Nanoanalysis (DCN) Center for Advancing Electronics Dresden (cfaed) Dresden University of Technology Helmholtzstraße 18 01069 Dresden Germany

Helmholtz‐Zentrum Dresden Rossendorf Bautzner Landstraße 400 01328 Dresden Germany

Dresden Integrated Center for Applied Physics and Photonic Materials Dresden University of Technology Nöthnitzer Str. 61 01187 Dresden Germany

Light microscopy facility of the Center for Molecular and Cellular Bioengineering (CMCB) Dresden University of Technology 01062 Dresden Germany

Institute for Geosciences Johannes Gutenberg University Mainz 55099 Mainz Germany

Physics of Life DFG Cluster of Excellence TU Dresden 01062 Dresden Germany

Funding

Deutsche Forschungsgemeinschaft

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