journal article·2021-09Open access

Atomically‐Precise Texturing of Hexagonal Boron Nitride Nanostripes

Khadiza Ali, Laura Fernández, Mohammad A. Kherelden, Anna A. Makarova, Igor Píš, Federica Bondino, James Lawrence, Dimas G. de Oteyza, Dmitry Yu. Usachov, Denis V. Vyalikh, F. Javier García de Abajo, Zakaria M. Abd El‐Fattah, J. Enrique Ortega, Frederik Schiller

Advanced Science· Volume 8· Issue 17

Abstract

Abstract Monolayer hexagonal boron nitride (hBN) is attracting considerable attention because of its potential applications in areas such as nano‐ and opto‐electronics, quantum optics and nanomagnetism. However, the implementation of such functional hBN demands precise lateral nanostructuration and integration with other two‐dimensional materials, and hence, novel routes of synthesis beyond exfoliation. Here, a disruptive approach is demonstrated, namely, imprinting the lateral pattern of an atomically stepped one‐dimensional template into a hBN monolayer. Specifically, hBN is epitaxially grown on vicinal Rhodium (Rh) surfaces using a Rh curved crystal for a systematic exploration, which produces a periodically textured, nanostriped hBN carpet that coats Rh(111)‐oriented terraces and lattice‐matched Rh(337) facets with tunable width. The electronic structure reveals a nanoscale periodic modulation of the hBN atomic potential that leads to an effective lateral semiconductor multi‐stripe. The potential of such atomically thin hBN heterostructure for future applications is discussed.
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Research context

OpenAlex topics: Graphene research and applications · 2D Materials and Applications · Quantum and electron transport phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Centro de Física de Materiales CSIC/UPV‐EHU‐Materials Physics Center San Sebastián E‐20018 Spain

Universidad del País Vasco Dpto. Física Aplicada San Sebastián E‐20018 Spain

Physics Dept. Faculty of Science Al‐Azhar University Nasr City Cairo E‐11884 Egypt

Freie Universität Berlin Berlin 14195 Germany

IOM‐CNR Laboratorio TASC Trieste I‐34149 Italy

Elettra ‐ Sincrotrone Trieste S.C.p.A. Trieste I‐34149 Italy

Donostia International Physics Center San Sebastián E‐20018 Spain

St. Petersburg State University St. Petersburg 199034 Russia

Ikerbasque Basque Foundation for Science Basque Country Bilbao 48013 Spain

ICFO‐Institut de Ciencies Fotoniques The Barcelona Institute of Science and Technology Barcelona 08860 Spain

ICREA‐Institució Catalana de Recerca i Estudis Avançats Passeig Lluís Companys 23 Barcelona 08010 Spain

Funding

Ministerio de Ciencia, Innovación y Universidades · Eusko Jaurlaritza

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