journal article·2012-06

Hybrid graphene–quantum dot phototransistors with ultrahigh gain

Gerasimos Konstantatos, Michela Badioli, Louis Gaudreau, Johann Osmond, Maria Bernechea, F. Pelayo Garcia de Arquer, Fabio Gatti, Frank H. L. Koppens

Nature Nanotechnology· Volume 7· Issue 6
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Abstract

Graphene is an attractive material for optoelectronics and photodetection applications because it offers a broad spectral bandwidth and fast response times. However, weak light absorption and the absence of a gain mechanism that can generate multiple charge carriers from one incident photon have limited the responsivity of graphene-based photodetectors to ∼10(-2) A W(-1). Here, we demonstrate a gain of ∼10(8) electrons per photon and a responsivity of ∼10(7) A W(-1) in a hybrid photodetector that consists of monolayer or bilayer graphene covered with a thin film of colloidal quantum dots. Strong and tunable light absorption in the quantum-dot layer creates electric charges that are transferred to the graphene, where they recirculate many times due to the high charge mobility of graphene and long trapped-charge lifetimes in the quantum-dot layer. The device, with a specific detectivity of 7 × 10(13) Jones, benefits from gate-tunable sensitivity and speed, spectral selectivity from the short-wavelength infrared to the visible, and compatibility with current circuit technologies.
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Research context

OpenAlex topics: Graphene research and applications · Quantum and electron transport phenomena · Nanowire Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Bonaccorso, F., Sun, Z., Hasan, T. & Ferrari, A. C. Graphene photonics and optoelectronics. Nature Photon. 4, 611–622 (2010).10.1038/nphoton.2010.186 ↗
2. Park, J., Ahn, Y. H. & Ruiz-Vargas, C. Imaging of photocurrent generation and collection in single-layer graphene. Nano Lett. 9, 1742–1746 (2009).10.1021/nl8029493 ↗
3. Lee, E. J. H., Balasubramanian, K., Weitz, R. T., Burghard, M. & Kern, K. Contact and edge effects in graphene devices. Nature Nanotech. 3, 486–490 (2008).10.1038/nnano.2008.172 ↗
4. Xia, F. et al. Photocurrent imaging and efficient photon detection in a graphene transistor. Nano Lett. 9, 1039–1044 (2009).10.1021/nl8033812 ↗
5. Xia, F., Mueller, T., Lin, Y. M., Valdes-Garcia, A. & Avouris, P. Ultrafast graphene photodetector. Nature Nanotech. 4, 839–843 (2009).10.1038/nnano.2009.292 ↗
6. Mueller, T., Xia, F. & Avouris, P. Graphene photodetectors for high-speed optical communications. Nature Photon. 4, 297–301 (2010).10.1038/nphoton.2010.40 ↗
7. Lemme, M. et al. Gate-activated photoresponse in a graphene p–n junction. Nano Lett. 11, 4134–4137 (2011).10.1021/nl2019068 ↗
8. Gabor, N. M. et al. Hot carrier–assisted intrinsic photoresponse in graphene. Science 334, 648–652 (2011).10.1126/science.1211384 ↗
9. Song, J. C. W., Rudner, M. S., Marcus, C. M. & Levitov, L. S. Hot carrier transport and photocurrent response in graphene. Nano Lett. 11, 4688–4692 (2011).10.1021/nl202318u ↗
10. Echtermeyer, T. J. et al. Strong plasmonic enhancement of photovoltage in graphene. Nature Commun. 2, 458 (2011).10.1038/ncomms1464 ↗
11. Koppens, F. H. L., Chang, D. E. & García de Abajo, F. J . Graphene plasmonics: a platform for strong light–matter interactions. Nano Lett. 11, 3370–3377 (2011).10.1021/nl201771h ↗
12. Thongrattanasiri, S., Koppens, F. H. L. & Garcia de Abajo, F. J. Complete optical absorption in periodically patterned graphene. Phys. Rev. Lett. 108, 047401 (2012).10.1103/PhysRevLett.108.047401 ↗
13. Furchi, M. et al. Microcavity-integrated graphene photodetector. Preprint at http://arXiv.org/abs/1112.1549 (2011).
14. Engel, M. et al. Light–matter interaction in a microcavity-controlled graphene transistor. Preprint at http://arXiv.org/abs/1112.1380 (2011).
15. Shields, A. J. et al. Detection of single photons using a field-effect transistor gated by a layer of quantum dots. Appl. Phys. Lett. 76, 3673–3675 (2000).10.1063/1.126745 ↗
16. Gansen, E. J. et al. Photon-number-discriminating detection using a quantum-dot, optically gated, field-effect transistor. Nature Photon. 1, 585–588 (2007).10.1038/nphoton.2007.173 ↗
17. Wright, P. D., Nelson, R. J. & Cella, T. High-gain InGaAsP-InP heterojunction phototransistors. Appl. Phys. Lett. 37, 192–194 (1980).10.1063/1.91821 ↗
18. Leu, L. Y., Gardner, J. T. & Forrest, S. R. A high gain, high bandwidth In0.53Ga0.47As/InP heterojunction phototransistor for optical communications. J. Appl. Phys. 69, 1052–1062 (1991).10.1063/1.347371 ↗
19. Ogura, M. Hole injection type InGaAs–InP near infrared photo-FET (HI-FET). IEEE J. Quantum Electron. 46, 562–569 (2010).10.1109/JQE.2009.2033130 ↗
20. Konstantatos, G. & Sargent, E. H. Nanostructured materials for photon detection. Nature Nanotech. 5, 391–400 (2010).10.1038/nnano.2010.78 ↗
21. Konstantatos, G. et al. Ultrasensitive solution-cast quantum dot photodetectors. Nature 442, 180–183 (2006).10.1038/nature04855 ↗
22. Lee, J. S., Kovalenko, M. V., Huang, J., Chung, D. S. & Talapin, D. V. Band-like transport, high electron mobility and high photoconductivity in all-inorganic nanocrystal arrays. Nature Nanotech. 6, 348–352 (2011).10.1038/nnano.2011.46 ↗
23. Dean, C. R. et al. Boron nitride substrates for high-quality graphene electronics. Nature Nanotech. 5, 722–726 (2010).10.1038/nnano.2010.172 ↗
24. Manga, K. K., Zhou, Y., Yan, Y. & Loh, K. P. Multilayer hybrid films consisting of alternating graphene and titania nanosheets with ultrafast electron transfer and photoconversion properties. Adv. Funct. Mater. 19, 3638–3643 (2009).10.1002/adfm.200900891 ↗
25. Lee, Y. et al. Wafer-scale synthesis and transfer of graphene films. Nano Lett. 10, 490–493 (2010).10.1021/nl903272n ↗
26. Reina, A. et al. Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Lett. 9, 30–35 (2009).10.1021/nl801827v ↗
27. Li, X. et al. Large-area synthesis of high-quality and uniform graphene films on copper foils. Science 324, 1312–1314 (2009).10.1126/science.1171245 ↗
28. Bae, S. et al. Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nature Nanotech. 5, 574–578 (2010).10.1038/nnano.2010.132 ↗
29. Konstantatos, G., Levina, L., Fischer, A. & Sargent, E. H. Engineering the temporal response of photoconductive photodetectors via selective introduction of surface trap states. Nano Lett. 8, 1446–1450 (2008).10.1021/nl080373e ↗
30. Rose, A. Concepts in Photoconductivity and Allied Problems (Robert E. Krieger Publishing, 1978).
31. Peters, E. C. et al. Gate dependent photocurrents at a graphene p–n junction. Appl. Phys. Lett. 97, 193102 (2010).10.1063/1.3505926 ↗
32. George, P. A. et al. Ultrafast optical-pump terahertz-probe spectroscopy of the carrier relaxation and recombination dynamics in epitaxial graphene. Nano Lett. 8, 4248–4251 (2008).10.1021/nl8019399 ↗
33. Dawlaty, J. M. et al. Measurement of the optical absorption spectra of epitaxial graphene from terahertz to visible. Appl. Phys. Lett. 93, 131905 (2008).10.1063/1.2990753 ↗
34. Schedin, F. et al. Detection of individual gas molecules adsorbed on graphene. Nature Mater. 6, 652–655 (2007).10.1038/nmat1967 ↗
35. Moser, J. & Bachtold, A. Fabrication of large addition energy quantum dots in graphene. Appl. Phys. Lett. 95, 173506 (2009).10.1063/1.3243690 ↗