journal article·2023-11-29

Spectroscopic Evidence of Localized Small Polarons in Low-Dimensional Ionic Liquid Lead-Free Hybrid Perovskites

Riki Subagyo, Pramitha Y. D. Maulida, Dominik Kowal, Sri Hartati, Rossyaila M. Muslimawati, Yulfi Zetra, Lina J. Diguna, Syafsir Akhlus, Muhammad H. Mahyuddin, Lei Zhang, Chi S. Tang, Caozheng Diao, Andrew T. S. Wee, Muhammad D. Birowosuto, Arramel, Andrivo Rusydi, Yuly Kusumawati

ACS Applied Materials & Interfaces· Volume 15· Issue 47
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Abstract

Rational design is an important approach to consider in the development of low-dimensional hybrid organic–inorganic perovskites (HOIPs). In this study, 1-butyl-1-methyl pyrrolidinium (BMP), 1-(3-aminopropyl)imidazole (API), and 1-butyl-3-methyl imidazolium (BMI) serve as prototypical ionic liquid components in bismuth-based HOIPs. Element-sensitive X-ray absorption spectroscopy measurements of BMPBiBr 4 and APIBiBr 5 reveal distinct resonant excitation profiles across the N K-edges, where contrasting peak shifts are observed. These 1D-HOIPs exhibit a large Stokes shift due to the small polaron contribution, as probed by photoluminescence spectroscopy at room temperature. Interestingly, the incorporation of a small fraction of tin (Sn) into the APIBiBr 5 (Sn/Bi mole ratio of 1:3) structure demonstrates a strong spectral weight transfer accompanied by a fast decay lifetime (2.6 ns). These phenomena are the direct result of Sn-substitution in APIBiBr 5, decreasing the small polaron effect. By changing the active ionic liquid, the electronic interactions and optical responses can be moderately tuned by alteration of their intermolecular interaction between the semiconducting inorganic layers and organic moieties.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Quantum Dots Synthesis And Properties · Advanced Thermoelectric Materials and Devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Kampus ITS Keputih, Sukolilo, Surabaya 60111, Indonesia

Nano Center Indonesia, Jl PUSPIPTEK, South Tangerang, Banten 15314, Indonesia

Łukasiewicz Research Network─PORT Polish Center for Technology Development, Stabłowicka 147, Wrocław 54-066, Poland

Doctoral Program of Engineering Physics, Faculty of Industrial Technology, Institut Teknologi Bandung, Bandung 40132, Indonesia

Quantum and Nano Technology Research Group, Faculty of Industrial Technology, Institut Teknologi Bandung, Bandung 40132, Indonesia

Department of Renewable Energy Engineering, Universitas Prasetiya Mulya, Kavling Edutown I.1, Jl. BSD Raya Utama, BSD City, Tangerang 15339, Indonesia

Research Center for Nanoscience and Nanotechnology, Institut Teknologi Bandung, Bandung 40132, Indonesia

Department of Physics, National University of Singapore, Singapore 117551, Singapore

Singapore Synchrotron Light Source (SSLS), National University of Singapore, Singapore 117603, Singapore

NUS Graduate School for Integrative Sciences and Engineering, National University of Singapore, Singapore 117456, Singapore

Centre for Advanced 2D Materials, National University of Singapore, 6 Science Drive 2, Singapore 117546, Singapore

Funding

Institut Teknologi Bandung · Institut Teknologi Sepuluh Nopember · Asian Development Bank · Ministry of Education - Singapore · Narodowe Centrum Nauki · National University of Singapore · PT Nanotech Indonesia Global Tbk

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