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ACS APPLIED MATERIALS & INTERFACES

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Integration of the Triboelectric Effect into a Yolk-Shell Conjugated Microporous Polymer for Enhanced Artificial Photosynthesis

Shaojie You, Yu Yang, Jihui Cao, Wenjun Fu et al.

Conjugated microporous polymers (CMPs) have demonstrated considerable potential in the field of photocatalytic organic synthesis. However, the issue of intrinsic photogenerated carrier recombination severely limits their potential applications. Herein, a strategy for boosting the photocatalytic performance of CMP through the triboelectric effect is proposed. Specifically, the b…

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A Recyclable Biomimetic Flexible Sensor Based on Gallium-Based Liquid Metal for Real-Time ECG Signal Monitoring

Jun Xu, Leran Kuai, Peihong Yu, Yuxiao Zhao et al.

Gallium-based liquid metal (Ga-LM) has high electrical conductivity, excellent deformability, recyclability, and biocompatibility, simultaneously satisfying the core requirements of stretchable ECG sensors: high signal-to-noise ratio (SNR), low interfacial impedance, and conformability. A recyclable biomimetic flexible sensor based on Ga-LM was prepared in this study. Nanofiber…

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Engineering Tunable Microneedle Arrays Through Visible Light-Mediated PET-RAFT 3D Printing

Sahil Premprakash Wankhede, Laura Casado Mayo, Cathal J. Kearney, Ali Bagheri et al.

3D printing has enabled the development of patient-specific drug delivery systems and medical devices. Here, we report the fabrication of microneedle arrays using visible light-mediated photoinduced electron/energy-transfer-reversible addition-fragmentation chain transfer (PET-RAFT) polymerization via digital light processing (DLP) 3D printing. A series of formulations based on…

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A General Strategy for an Efficient Biointerface via Enhanced Capacitive Coupling

Ting Xue, Zhiyuan Tan, Weiwei Xia, Yicheng Yang et al.

Reliable sensing of bioelectronic signals is highly dependent on the efficient charge transfer at the biointerface, and the incorporation of biointerface materials would enhance it. Nevertheless, systematic investigations on interfacial electrochemical dynamics remain lacking, and universal fabrication criteria for such biointerface materials are yet to be established. Here, we…

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A Multiscale-Designed Ceramic Nanofiber Aerogel with High-Temperature Mechanical Superelasticity and Thermal Superinsulation

Xin Long, Min Hu, Jianan Qin, Lichun Zhou et al.

Thermal insulation in extreme environments, such as aerospace, geothermal settings, and thermoelectric applications, demands materials with excellent structural stability and outstanding thermal insulation capabilities. Ceramic nanofiber aerogels have contributed to overcoming the mechanical limitations, such as the high brittleness of ceramic aerogels based on zero-dimensional…

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Multimodal Operando Characterization of Layering and Wear at Concentrated Polymer Brush Interfaces

Hikaru Okubo, Daiki Kagiwata, Toru Takeuchi, Ken Nakano et al.

A multimodal operando measurement system integrating a surface force apparatus, optical interferometry, and Raman spectroscopy was developed to investigate layering, molecular-state evolution, and wear at concentrated polymer brush (CPB) interfaces in a good solvent. The system enables simultaneous monitoring of mechanical responses, interfacial gap, and molecular behavior at s…

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A Flexible PPDO- co -PEG-Based Copolymer Tissue Patch with High Interfacial and Cohesive Strength for Reliable Sealing and Rapid Closure of Wet Tissue

Lan-Xi Yan, Jie Zhang, Xiao-Hu Chen, Yu-Tao Cao et al.

Tissue patches have gained widespread attention for their ability to rapidly and effectively close tissue wounds. Nevertheless, maintaining robust adhesive strength under physiological conditions remains a significant challenge for current tissue adhesion materials. Herein, a tissue patch material based on a poly(p-dioxanone)-co-poly(ethylene glycol) (PPDO-co-PEG) copolymer is …

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Dual-Mode Field-Deployable Platform Based on Self-Assembled Magnetic Probes for Simultaneous Monitoring of Chikungunya Virus and Host Immune Status

Junyan Ai, Jiaxuan Li, Qian Wang, Tao Zhang et al.

Real-time dual monitoring of pathogen burden and host immune response enables risk stratification and precision therapy, yet remains technically challenging. Addressing the needs of chikungunya fever outbreak control, here, we developed a flexible, ultrasensitive dual-mode lateral flow immunoassay (LFA) capable of simultaneous detection of chikungunya virus (CHIKV) antigen and …

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Design of High-Performance, Robust, and Recyclable Epoxy Resins

Vatsalya Gupta, Ramkrishna Sarkar

The inherent non-recyclability of epoxy resins (ERs), a major sustainability barrier, can be addressed by incorporating dynamic covalent linkages. However, conventional approaches to design reprocessable ERs typically require the preinstallation of dynamic motifs within monomers, making synthesis a multistep process. Besides, their thermal and mechanical robustness often remain…

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Molecular Additive Engineering for Process-Humidity Robustness and Reproducible Fabrication of Perovskite Solar Cells and Modules

Muhammad Mohsin Saeed, Hyoung Woo Kwon, You Li, Sheng Fu et al.

The commercialization of perovskite solar cells (PSCs) faces significant challenges due to their sensitivity to environmental humidity, which compromises film crystallization and device stability. Here, we introduce diphenylvinylphosphine (DPVP) as a Lewis base additive that enhances the performance and reproducibility of PSCs fabricated under ambient-air conditions. DPVP suppr…

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Impact of Amphiphilic Balance on Nano–Bio Interactions of Peptide Amphiphile Nanostructures

Karla Bonic, Kailin Mooney, Li Xiang, Sadik Esener et al.

Self-assembled peptide amphiphile (PA)-based nanostructures are promising biomaterials with their biocompatibility and highly tunable physical and chemical properties. Despite this promise, the interactions of PA nanostructures with biological systems have remained largely unexplored. Here, we investigate nano-bio interactions of self-assembled PA nanostructures using a series …

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Chiral Organo-Soluble Carbon Nanocolloids with Dual-Mode Optical Responsiveness: From Nonpolar Enantioselective Sensing to Lead−Halide Perovskite Passivation

Anna A. Vedernikova, Alexander M. Mitroshin, Aleksandr P. Litvin, Jinfeng Xie et al.

A major challenge in chiral carbon nanoparticles is to create materials whose chirality persists outside aqueous environments and remains functional under organic synthesis, interfacial engineering, and device fabrication conditions. We overcome this barrier by developing intrinsically chiral, organo-soluble carbon nanocolloids (CNCs) through solvent-free thermal condensation o…

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Deferoxamine-B–Functionalized Silicon Nanowire Field-Effect Transistor Interfaces for Ultralow-Concentration Fe 3+ Detection in Semiconductor Process Chemicals

Bharath Kumar Yadlapalli, Tzu-Chen Huang, Yu-Hsiang Lee, Yu-Che Cheng et al.

Maintaining ultralow metal-ion purity in process chemicals is crucial in semiconductor fabrication, where trace Fe3+ contamination can lead to dielectric breakdown, yield loss, and unintended doping. Inductively coupled plasma mass spectrometry (ICP-MS) provides excellent qualitative and quantitative sensitivity; however, it requires specialized infrastructure, is time-consumin…

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Measurement-Informed Deep Learning for Real-Time Monitoring of Hydrodynamic Drying Dynamics in Inkjet-Printed Display Pixels via Low-Resolution Imaging

Sung Jun Park, Donggeun Park, Jin Hong Park, Jae Yeong Jeong et al.

Real-time monitoring of drying dynamics is critical for ensuring high-quality thin-film fabrication in inkjet printing. Here, we present a classification framework for the drying stages of ZnO nanoparticle inks on 200-PPI patterned substrates using low-resolution optical images. By correlating 3D surface profiles with visual textures, we show how the volatility mismatch and vis…

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Graphene-Graphene Oxide Interfaces Enable Moisture-Tolerant Solid Lubrication

Mingi Choi, Anirudha V. Sumant, Won-Seok Kim, Seongyun Lee et al.

Protecting sliding surfaces from friction and wear remains a persistent engineering challenge. Graphene oxide (GO) and pristine graphene (PG), the two different carbon-based 2D materials, are attractive solid-lubricant coatings, but both are compromised by moisture. GO readily forms a protective transfer layer at the sliding contact through the reactive, adhesive chemistry of i…

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Future of Zeolites: Synthesis and Application

Wenfu Yan, Jihong Yu

Zeolites have played a transformative role in catalysis, adsorption, and ion exchange for more than half a century. Recent years have witnessed a renewed surge of innovation propelled by advances in framework discovery, mechanistic understanding, precision synthesis, and data-driven materials design. This review summarizes key developments in zeolite research achieved during th…

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Synergistic Photonic Sintering of Robust Cu@AgNWs for Environmentally Stable Electromagnetic Interference Shielding and High-Response Thermal Management

Zhenfeng Li, Yifan Zhao, Jianhang Shao, Zixu Wang et al.

Copper nanowires (CuNWs) present a promising low-cost alternative to indium tin oxide for next-generation flexible electronics. However, their widespread use is hindered by their natural tendency to oxidize and the difficulty of establishing effective interwire connections on thermally sensitive substrates. Here, we introduce durable, oxidation-resistant transparent conductive …

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Sustainable Visible-Light Photoinitiation Enabled by a Bio-Based Photosensitizer/Oxime Ester Combination via Triplet–Triplet Energy Transfer

Kaidan Yang, Margot Manivel, Coralie Ohl, Céline Dietlin et al.

AC:AC:Visible-light photopolymerization offers safer processing, lower energy input, and broader compatibility with advanced manufacturing than thermally initiated curing or short-wavelength UV processes. However, sustainable photoinitiating systems that operate efficiently under visible light remain limited. Here, a sustainable two-component strategy is reported by combining b…

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