Viable Regiochemical Control in Semiconducting Polymers for Field-Effect Transistors: From High-Mobility Enhancement toward High Deformability
Source abstract
Abstract
The molecular properties of semiconducting polymers with regioisomeric structural factors can be effectively tuned based on their regiochemistry. Thus, the molecular dynamics, intermolecular stacking, and film morphology of these polymers have been tuned via regiochemical control to ultimately enhance their electronic properties in organic field-effect transistors (OFETs). This strategy can also be employed to induce high deformability in organic electronics. In this review, studies on the regiochemistry of conjugated polymers based on the dimensions of regiochemical factors and synthesis methods are summarized to enable the control of the regiochemistry of substituents, side chains, and backbone linkages that can impact their optoelectronic properties and solid-state morphologies. Moreover, technological developments in the fabrication of OFETs with highly enhanced mobility toward stretchable electronics have been discussed.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Luminescence and Fluorescent Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Energy Engineering, School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), 50 UNIST-gil, Eonyang-eup, Ulju-gun, Ulsan 44919, Republic of Korea
Department of Chemistry, McGill University, 801 Sherbrooke St West, Montreal, Quebec H3A 0B8, Canada
Department of Applied Chemistry, Dong-Eui University, 176 Eomgwangro, Busan 47340, Republic of Korea
Department of Cosmetics Engineering
Dong-Eui University 176 Eomgwangro
Graduate School of Carbon Neutrality, Ulsan National Institute of Science and Technology (UNIST), 50 UNIST-gil, Ulju-gun, Ulsan 44919, Republic of Korea
Funding
National Research Foundation of Korea · Korea Institute of Energy Technology Evaluation and Planning
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