journal article·2024-09-18

Interface Engineering by Unsubstituted Pristine Nickel Phthalocyanine as Hole Transport Material for Efficient and Stable Perovskite Solar Cells

Mustafa Haider, Farhan Mudasar, Junliang Yang, Sergey Makarov

ACS Applied Materials & Interfaces· Volume 16· Issue 37
Publisher page

Abstract

Lead halide perovskite solar cells (PSCs) have been rapidly developed in the past decade. With the development of a PSC, interface engineering plays an increasingly important role in maximizing device performance and long-term stability. We report a simple and effective interface engineering method for achieving improvement of PSCs up to 20% by employing unsubstituted pristine nickel phthalocyanine (NiPc). Thermal annealing of NiPc improves the interface between NiPc and perovskite because of the incorporation of NiPc molecules into the perovskite grain boundaries, which creates improvements in hole extraction from the perovskite absorber layer, as evidenced by time-resolved photoluminescence measurements. This significantly improves the charge transfer and collection efficiency, which are closely related to the improvement of the interface between perovskite and NiPc.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Chalcogenide Semiconductor Thin Films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Powder Metallurgy, School of Physics, Central South University, Changsha 410083, China

Advance Solar Technology Institute, Xuancheng 242000, China

Department of Physical and Environmental Sciences, University of Toronto Scarborough, Toronto, ON M1C 1A4, Canada

School of Physics and Engineering, ITMO University, Kronverkskiy pr. 49, St. Petersburg 197101, Russia

Qingdao Innovation and Development Centre, Harbin Engineering University, Qingdao, Shandong 266000, China

Funding

Ministry of Science and Technology of the People's Republic of China · Ministry of Science and Higher Education of the Russian Federation

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