journal article·2023-12-02

Monodentate versus Bidentate Anchoring Groups in Self-Assembling Molecules (SAMs) for Robust p–i–n Perovskite Solar Cells

Eyyup Yalcin, Ece Aktas, Maria Mendéz, Emre Arkan, José G. Sánchez, Eugenia Martínez-Ferrero, Francesco Silvestri, Esther Barrena, Mustafa Can, Serafettin Demic, Emilio Palomares

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Abstract

Current improvement in perovskite solar cells (PSCs) has been achieved by interface engineering and fine-tuning of charge-selective contacts. In this work, we report three novel molecules that can form self-assembled layers (SAMs) as an alternative to the most commonly used p-type contact material, PTAA. Two of these molecules have bidentate anchoring groups (MC-54 and MC-55), while the last one is monodentate (MC-45). Besides the PTAA comparison, we also compared those two types of molecules and their effect on the solar cell's performance. Devices fabricated with MC-54 and MC-55 showed a remarkable field factor (about 80%) and a better current density, leading to higher efficient solar cells in comparison to MC-45 and PTAA. Moreover, mono- and bidentate present higher stability and reproducibility in comparison to PTAA.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Ondokuz Mayıs University, Metallurgy and Materials Engineering Department, 55030 Samsun, Turkey

Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, E-43007 Tarragona, Spain

University of Silesia, Institute of Chemistry, Szkolna, 40-006 Katowice, Poland

Institut de Ciencia de Materials de Barcelona, ICMAB-CSIC, Campus UAB, 08193 Bellaterra, Spain

Department of Engineering Science, Izmir Katip Celebi University, 35620 Izmir, Turkey

Graphene Application & Research Center, Izmir Katip Celebi University, 35620 Izmir, Turkey

Department of Materials Science and Engineering, Izmir Katip Celebi University, 35620 Izmir, Turkey

ICREA, Paseig Lluis Compays, 23, E-08010 Barcelona, Spain

Funding

Ministerio de Ciencia e Innovaci?n · Ag?ncia de Gesti? d'Ajuts Universitaris i de Recerca · Institut Catal? d'Investigaci? Qu?mica · Y?ksek?gretim Kurulu · Centres de Recerca de Catalunya · Generalitat de Catalunya · T?rkiye Bilimsel ve Teknolojik Arastirma Kurumu · Instituci? Catalana de Recerca i Estudis Avan?ats

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