journal article·2024-11-20Open access

Inkjet-Printed FASn1–xPbxI3-Based Perovskite Solar Cells

Ayush Tara, Vincent Schröder, Ananta Paul, Natalia Maticiuc, Manuel F. Vasquez-Montoya, Janardan Dagar, Susheel Sharma, Rockey Gupta, Emil J. W. List-Kratochvil, Eva L. Unger, Florian Mathies

ACS Applied Materials & Interfaces· Volume 16· Issue 46

Abstract

High Resolution Image Download MS PowerPoint Slide Metal halide perovskite solar cells (PSCs) have gained significant attention in thin-film photovoltaic research for their high power conversion efficiency (PCE) and facile fabrication processes. This study presents the use of inkjet printing to fabricate thin films of combinatorial mixed formamidinium tin-lead perovskites and evaluates their layer quality and device performance. Our findings demonstrate that incorporating Pb up to 50% into FASnI 3 films enhances lattice stability. The investigation focused on optimizing the composition ratio for improved photovoltaic performance with FASn 0.5 Pb 0.5 I 3 -based PSCs achieving the highest PCE of 10.26%. Additionally, these cells exhibited an absorption spectrum extending beyond 1000 nm, corresponding to a 1.25 eV bandgap. The results suggest that inkjet printing can effectively enhance the efficiency of tin–lead-based PSCs, supporting scalability in device manufacturing.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Chalcogenide Semiconductor Thin Films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Solution Processing of Hybrid Material and Devices, Helmholtz-Zentrum Berlin, Hahn-Meitner-Platz 1, 14109 Berlin, Germany

Department of Electronics, University of Jammu, 180006 Jammu, India

Helmholtz-Zentrum Berlin, Hahn-Meitner-Platz 1, 14109 Berlin, Germany

Department of Metallurgical Engineering and Material Science, Indian Institute of Technology Bombay, 400076 Mumbai, India

Institut für Physik, Institut für Chemie, Humboldt-Universität zu Berlin, Zum Großen Windkanal 2, 12489 Berlin, Germany

Department of Chemistry and Center of the Science of Materials (CSMB) Adlershof, Humboldt University of Berlin, 12489 Berlin, Germany

Funding

Helmholtz-Gemeinschaft · Indo-German Science and Technology Centre · Horizon 2020 Framework Programme

References (47)

Show source-provided references
1. 10.1126/science.aah555710.1126/science.aah5557 ↗
2. 10.1021/acs.accounts.5b0022910.1021/acs.accounts.5b00229 ↗
3. 10.1016/j.mattod.2013.12.00210.1016/j.mattod.2013.12.002 ↗
4. 10.1021/acs.accounts.5b0054010.1021/acs.accounts.5b00540 ↗
5. 10.1039/C6TC04830G10.1039/C6TC04830G ↗
6. 10.1021/acs.chemmater.6b0046610.1021/acs.chemmater.6b00466 ↗
7. 10.1126/science.124398210.1126/science.1243982 ↗
8. 10.1021/acs.jpclett.5b0018210.1021/acs.jpclett.5b00182 ↗
9. 10.3390/nano1012256910.3390/nano10122569 ↗
10. 10.1016/j.jechem.2018.12.00510.1016/j.jechem.2018.12.005 ↗
11. 10.1515/nanoph-2019-057210.1515/nanoph-2019-0572 ↗
12. 10.1002/advs.20170025610.1002/advs.201700256 ↗
13. 10.1007/978-981-10-7206-2_1610.1007/978-981-10-7206-2_16 ↗
14. 10.1039/C8SE00368H10.1039/C8SE00368H ↗
15. 10.1021/acsami.0c1454010.1021/acsami.0c14540 ↗
16. 10.1002/ente.20190099110.1002/ente.201900991 ↗
17. 10.1021/ja809598r10.1021/ja809598r ↗
18. 10.1038/s41586-023-05825-y10.1038/s41586-023-05825-y ↗
19. 10.1039/C4EE01076K10.1039/C4EE01076K ↗
20. 10.1038/nphoton.2014.8210.1038/nphoton.2014.82 ↗
21. 10.1021/acsenergylett.2c0077610.1021/acsenergylett.2c00776 ↗
22. 10.1002/adma.20230050310.1002/adma.202300503 ↗
23. 10.1038/s41467-021-22864-z10.1038/s41467-021-22864-z ↗
24. 10.1021/acs.jpcc.8b0104510.1021/acs.jpcc.8b01045 ↗
25. 10.1002/adfm.20210964910.1002/adfm.202109649 ↗
26. 10.1186/s40580-023-00371-910.1186/s40580-023-00371-9 ↗
27. 10.1021/jz500211710.1021/jz5002117 ↗
28. 10.1021/jz502547f10.1021/jz502547f ↗
29. 10.1039/C8TA11891D10.1039/C8TA11891D ↗
30. 10.1021/acscentsci.2c0107710.1021/acscentsci.2c01077 ↗
31. 10.1002/aenm.20220389810.1002/aenm.202203898 ↗
32. 10.1007/s10118-023-2961-z10.1007/s10118-023-2961-z ↗
33. 10.17815/jlsrf-2-8410.17815/jlsrf-2-84 ↗
34. 10.1103/PhysRevE.62.75610.1103/PhysRevE.62.756 ↗
35. 10.1039/D1MA00494H10.1039/D1MA00494H ↗
36. 10.1039/C6TA11181E10.1039/C6TA11181E ↗
37. 10.1016/j.nanoen.2023.10865310.1016/j.nanoen.2023.108653 ↗
38. 10.1021/jacs.8b0594910.1021/jacs.8b05949 ↗
39. 10.1016/j.matchemphys.2019.12202110.1016/j.matchemphys.2019.122021 ↗
40. 10.1021/acsenergylett.3c0261710.1021/acsenergylett.3c02617 ↗
41. 10.1039/D3TA06654A10.1039/D3TA06654A ↗
42. 10.1002/adfm.20230452310.1002/adfm.202304523 ↗
43. 10.1038/nmeth.208910.1038/nmeth.2089 ↗
44. 10.1021/ja503325910.1021/ja5033259 ↗
45. 10.1021/cm970568f10.1021/cm970568f ↗
46. 10.1021/cm010167710.1021/cm0101677 ↗
47. 10.1002/adma.20180370310.1002/adma.201803703 ↗