Zero-Strain Sodium Lanthanum Titanate Perovskite Embedded in Flexible Carbon Fibers as a Long-Span Anode for Lithium-Ion Batteries

“High-capacity” graphite and “zero-strain” spinel Li 4 Ti 5 O 12 (LTO) occupy the majority market of anode materials for Li + storage in commercial applications. Nevertheless, their intrinsic drawbacks including the unsafe potential of graphite and unsatisfactory capacity of LTO limit the further development of lithium-ion batteries (LIBs), which is unable to satisfy the ever-increasing demands. Here, a novel Na 0.35 La 0.55 TiO 3 perovskite embedded in multichannel carbon fibers (NLTO-NF) is rationally designed and synthesized through an electrospinning method. It not only has the advantages of a respectable specific capacity of 265 mAh g –1 at 0.1 A g –1 and superb rate capability, but it also possesses the zero-strain characteristic. Impressively, an ultralong cycling life with 96.3% capacity retention after 9000 cycles at 2 A g –1 is achieved in the half cell, and 90.3% of capacity retention ratio is obtained after even 2500 cycles at 1 A g –1 in the coupled LiFePO 4 /NLTO-NF full cell. This study introduces a new member with excellent performance to the zero-strain materials family for next-generation LIBs.