DataVXACS Applied Materials & InterfacesPaper
journal article·2021-05-12Open access

Interfacial versus Bulk Properties of Hole-Transporting Materials for Perovskite Solar Cells: Isomeric Triphenylamine-Based Enamines versus Spiro-OMeTAD

Jurate Simokaitiene, Monika Cekaviciute, Kristina Baucyte, Dmytro Volyniuk, Ranush Durgaryan, Desiré Molina, Bowen Yang, Jiajia Suo, YeonJu Kim, Demetrio Antonio da Silva Filho, Anders Hagfeldt, Gjergji Sini, Juozas V. Grazulevicius

ACS Applied Materials & Interfaces· Volume 13· Issue 18
Publisher pageOpen full text
Source abstract

Abstract

/V·s, which are higher than those in spiro-OMeTAD at the same electric fields. DFT-based analysis points to the presence of several conformers close in energy at room temperature. The newly synthesized hole-transporting materials (HTMs) were used in perovskite solar cells and exhibited performances comparable to that of spiro-OMeTAD. The device containing one newly synthesized hole-transporting enamine was characterized by a power conversion efficiency of 18.4%. Our analysis indicates that the perovskite-HTM interface dominates the properties of perovskite solar cells. PL measurements indicate smaller efficiency for perovskite-to-new HTM hole transfer as compared to spiro-OMeTAD. Nevertheless, the comparable power conversion efficiencies and simple synthesis of the new compounds make them attractive candidates for utilization in perovskite solar cells.
Source: openalex_inverted_index · Quality: baseline

Research context

Electronic materials

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Organic Electronics and Photovoltaics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilenu Road 19, LT, 50245 Kaunas, Lithuania

Department of Chemistry, Laboratory of Photomolecular Science Institute of Chemical Sciences Engineering, École Polytechnique Federale de Lausanne, 1015 Lausanne, Switzerland

Área de Química Orgánica, Instituto de Bioingeniería, Universidad Miguel Hernández, Avda. de la Universidad, s/n, 03202 Elche, Spain

Laboratoire de Physicochimie des Polymères et des Interfaces, EA 2528, CY Cergy Paris Université, 5 mail Gay Lussac, 95031 Cergy Pontoise Cedex, France

Institute for Advanced Studies, University of Cergy-Pontoise, 1 rue Descartes, 95000 Neuville-sur-Oise, France

Institute of Physics, University of Brasilia, 70919-970 Brasilia, Brazil

Funding

Agence Nationale de la Recherche · Funda??o de Apoio ? Pesquisa do Distrito Federal · Lietuvos Mokslo Taryba · Conselho Nacional de Desenvolvimento Cient?fico e Tecnol?gico · European Social Fund · Decanato de Pesquisa e Inova??o, Universidade de Bras?lia

References (54)

Show source-provided references
1. 10.1039/c9cs90020a10.1039/c9cs90020a ↗
2. 10.1016/j.rser.2017.09.09410.1016/j.rser.2017.09.094 ↗
3. 10.1016/j.rser.2017.02.08110.1016/j.rser.2017.02.081 ↗
4. 10.1038/s41560-018-0323-910.1038/s41560-018-0323-9 ↗
5. 10.1002/smll.20190085410.1002/smll.201900854 ↗
6. 10.1038/s41563-018-0071-z10.1038/s41563-018-0071-z ↗
7. 10.1038/s41560-018-0200-610.1038/s41560-018-0200-6 ↗
8. 10.1021/acsenergylett.7b0013710.1021/acsenergylett.7b00137 ↗
9. 10.1021/acsaem.0c0108510.1021/acsaem.0c01085 ↗
10. 10.1002/aenm.20150021310.1002/aenm.201500213 ↗
11. 10.1021/cr050134110.1021/cr0501341 ↗
12. 10.1038/2693610.1038/26936 ↗
13. 10.1016/s0379-6779(98)80033-710.1016/s0379-6779(98)80033-7 ↗
14. 10.1002/1521-4095(200007)12:14<1060::aid-adma1060>3.0.co;2-r10.1002/1521-4095(200007)12:14<1060::aid-adma1060>3.0.co;2-r ↗
15. 10.1039/c8cs00262b10.1039/c8cs00262b ↗
16. 10.1039/C9TA04166D10.1039/C9TA04166D ↗
17. 10.1002/adma.20160655510.1002/adma.201606555 ↗
18. 10.1039/C8TC04231D10.1039/C8TC04231D ↗
19. 10.1002/anie.20190370510.1002/anie.201903705 ↗
20. 10.1002/adma.20180373510.1002/adma.201803735 ↗
21. Sinicropi, J. A.; Cowdery-Corvan, J. R.; Magin, E. H.; Borsenberger, P. M. Hole Transport in N,N’-bis(2,2-diphenylvinyl)-N,N’-diphenylbenzidine-Doped Polymers. Proceedings of SPIE—The International Society for Optical Engineering, 1996; pp 192–201.10.1117/12.254245 ↗
22. 10.1016/j.synthmet.2008.06.03010.1016/j.synthmet.2008.06.030 ↗
23. 10.1039/b901847f10.1039/b901847f ↗
24. 10.1002/chem.20100004510.1002/chem.201000045 ↗
25. 10.1021/ol052558n10.1021/ol052558n ↗
26. 10.1021/ja051139i10.1021/ja051139i ↗
27. 10.1039/c1jm13962b10.1039/c1jm13962b ↗
28. 10.1039/c2tc00474g10.1039/c2tc00474g ↗
29. 10.1016/j.dyepig.2015.02.01310.1016/j.dyepig.2015.02.013 ↗
30. Borsenberger P. M. · 1998
31. 10.1039/c5tc02534f10.1039/c5tc02534f ↗
32. 10.1021/ct300326f10.1021/ct300326f ↗
33. 10.1021/acs.jctc.5b0114410.1021/acs.jctc.5b01144 ↗
34. 10.1021/acs.jctc.5b0043110.1021/acs.jctc.5b00431 ↗
35. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H. Gaussian 09, Revision B.01; Gaussian Inc: Wallingford, 2009.
36. 10.1021/acs.chemmater.8b0013610.1021/acs.chemmater.8b00136 ↗
37. 10.1039/c2jm14387a10.1039/c2jm14387a ↗
38. 10.1021/jp109643r10.1021/jp109643r ↗
39. 10.1021/cr050140x10.1021/cr050140x ↗
40. Bässler H. · 2011 · 1
41. 10.1021/cm049391x10.1021/cm049391x ↗
42. 10.1073/pnas.09214339910.1073/pnas.092143399 ↗
43. 10.1039/c9tc03515j10.1039/c9tc03515j ↗
44. 10.1021/ja058178e10.1021/ja058178e ↗
45. 10.1021/jp904946a10.1021/jp904946a ↗
46. 10.1002/pssb.222175010210.1002/pssb.2221750102 ↗
47. Arkhipov V. I. · 2006 · 350
48. 10.1039/d0ta00623h10.1039/d0ta00623h ↗
49. 10.1016/s0009-2614(00)00757-010.1016/s0009-2614(00)00757-0 ↗
50. 10.1002/adma.20040186610.1002/adma.200401866 ↗
51. 10.1002/cphc.20170049210.1002/cphc.201700492 ↗
52. Scheer, R.; Schock, H.W. Chalcogenide Photovoltaics: Physics, Technologies, and Thin Film Devices; Wiley, 2011; p 311. ISBN: 978-3-527-31459-1.10.1002/9783527633708 ↗
53. 10.1038/s41566-019-0398-210.1038/s41566-019-0398-2 ↗
54. 10.1126/science.aat358310.1126/science.aat3583 ↗