journal article·2020-09-09

Stable Silicene Wrapped by Graphene in Air

Yuting Nie, Stepan Kashtanov, Huilong Dong, Youyong Li, Yanyun Ma, Xuhui Sun

ACS Applied Materials & Interfaces· Volume 12· Issue 36
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Abstract

Silicene as a novel and unique two-dimensional nanomaterial attracts considerable research interest; however, obtaining free-standing silicene still poses challenges due to its instability in air. In this work, we report the synthesis of protected silicene through chemical vapor deposition (CVD), in which silicene is sandwiched by graphene (G@S@G) covered on a Cu substrate. Graphene plays the role of both a substrate and protector, which can help silicene stabilize in air. These findings were verified by means of advanced microscopic and spectroscopic investigations accompanied by density functional theory (DFT) simulations. A large area of G@S@G can be obtained and tailored in any type of shape based on the Cu film. G@S@G shows n-type semiconductor character confirmed by a field-effect transistor (FET) device.
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Research context

OpenAlex topics: Graphene research and applications · 2D Materials and Applications · Topological Materials and Phenomena

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University, 199 Ren’ai Road, Suzhou 215123, Jiangsu, P. R. China

Funding

State Administration of Foreign Experts Affairs · Collaborative Innovation Center of Suzhou Nano Science and Technology · Ministry of Education of the People's Republic of China · Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Priority Academic Program Development of Jiangsu Higher Education Institutions · Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University

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