Soft, Multifunctional, Robust Film Sensor Using a Ferroelectret with Significant Longitudinal and Transverse Piezoelectric Activity for Biomechanical Monitoring

Soft and intelligent bioelectronics have achieved unprecedented development in both academics and industries over the last few decades, especially as ideal body-worn detectors for continuous human health status monitoring. However, the longstanding functional stability of bioelectronics in multiple environmental conditions of variant temperatures, humidities, and mechanical stimuli or even in some extremes, such as ultraviolet radiation and X-ray radiation, has confined the application of these electronics. Herein, a self-sustainable, multifunctional, robust sensor for biomechanical monitoring is prepared by hybridizing a parallel-tunnel fluorinated poly(ethylene propylene) (FEP) ferroelectret film (sensing layer) and poly(dimethylsiloxane) (PDMS, protection layer). A fast response (80 ms) and a low pressure detection limit (10 Pa) were achieved. Notably, the self-powered sensor can not only sensitively detect the loading of solid objects but also percept liquid water droplets and airflow, which satisfies the diverse needs of wearable devices. Meanwhile, the capability of stable and repeatable operation under a wide temperature range (-26-70 °C), extreme moisture, continuous mechanical stimulus (∼1.08 million cycles), and long-time ultraviolet radiation enabled the extensive and long-term application of such sensors in multiple scenarios. Moreover, the reproducibility of sensing performance after X-ray radiation can be realized through second contact polarization even after encapsulation. Due to the inherent mechanical flexibility, the fabricated sensor was conformally attached to rough and deformed skin and verified the feasibility of wearable biomechanical sensing with high sensitivity from facial smiling to plantar movement. This work provides an efficient strategy for multifunctional sensing, holding great promise for advanced soft bioelectronics in the next generation of wearable intelligent electronic systems.