journal article·2016-07-27

A Dewetting-Induced Assembly Strategy for Precisely Patterning Organic Single Crystals in OFETs

Xiaonan Kan, Chengyi Xiao, Xinmeng Li, Bin Su, Yuchen Wu, Wei Jiang, Zhaohui Wang, Lei Jiang

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Abstract

Simple methods for patterning single crystals are critical to fully realize their applications in electronics. However, traditional vapor and solution methods are deficient in terms of crystals with random spatial and quality distributions. In this work, we report a dewetting-induced assembly strategy for obtaining large-scale and highly oriented organic crystal arrays. We also demonstrate that organic field-effect transistors (OFETs) fabricated from patterned n-alkyl-substituted tetrachloroperylene diimide (R-4ClPDI) single crystals can reach a maximum mobility of 0.65 cm(2) V(-1) s(-1) for C8-4ClPDI in ambient conditions. This technique constitutes a facile method for fabricating OFETs with high performances for large-scale electronics applications.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Block Copolymer Self-Assembly · Advanced Memory and Neural Computing

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Affiliations

Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Organic Solids and Laboratory of New Materials Institute of Chemistry, Chinese Academy of Sciences (ICCAS), Beijing, 100190, P. R. China

Department of Chemical Engineering, Monash University, Clayton, Victoria 3800, Australia

Laboratory of Bio-inspired Smart Interface Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. R. China

Funding

State Administration of Foreign Experts Affairs · Ministry of Education of the People's Republic of China · Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Chinese Academy of Sciences

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