Covalent Pinning of Highly Dispersed Ultrathin Metallic-Phase Molybdenum Disulfide Nanosheets on the Inner Surface of Mesoporous Carbon Spheres for Durable and Rapid Sodium Storage

Two-dimensional (2D) transition-metal dichalcogenide materials show potential for use in alkali metal ion batteries owing to their remarkable physical and chemical properties. Nevertheless, the electrochemical energy storage performance is still impaired by the tendency of aggregation, volume, and morphological change during the conversion reaction and poor intrinsic conductivity. Until now, ultrathin molybdenum disulfide nanosheets with a metallic-phase structure on the inner surface of mesoporous hollow carbon spheres (M-MoS2@HCS) have rarely been investigated as an anode for sodium-ion batteries. In this work, a novel M-MoS2@HCS anode was designed and synthesized by employing a template-assisted solvothermal reaction. Structural and chemical analyses indicate that the M-MoS2 nanosheets with a larger interlayer spacing compared to their semiconductor counterpart grow on the inner surface of HCS via covalent interactions. When used as the anode materials for Na+ storage, the M-MoS2@HCS anode presents durable and rapid sodium storage properties. The developed electrode shows a reversible capacity of 291.2 mAh g–1 at a high current density of 5 A g–1. After 100 cycles at 0.1 A g–1, the reversible capacity is 401.3 mAh g–1 with a capacity retention rate of 79%. After 2500 cycles at 1.0 A g–1, the electrode still delivers a reversible capacity of 320.1 mAh g–1 with a capacity retention rate of 75%. The excellent sodium storage capability of the MoS2@HCS electrode is explained by the special structural design, which reveals great potential to accelerate the practical applications of transition-metal dichalcogenide electrodes for sodium storage.