journal article·2016-12-21

Dithienobenzodithiophene-Based Small Molecule Organic Solar Cells with over 7% Efficiency via Additive- and Thermal-Annealing-Free Processing

Hyeng Gun Song, Yu Jin Kim, Ji Sang Lee, Yun-Hi Kim, Chan Eon Park, Soon-Ki Kwon

Publisher page

Abstract

Here we introduce a novel small molecule based on dithienobenzodithiophene and rhodanine, DTBDT-Rho, developed to study the effect of the rhodanine substitutuent on small molecule bulk heterojunction (BHJ) solar cells. DTBDT-Rho possesses distinct crystalline characteristics, sufficient solubility in chlorinated solvents, and broad absorption properties. Therefore, solution-processed BHJ photovoltaic cells made with DTBDT-Rho:PC 71 BM blends showed an extremely high power conversion efficiency (PCE; 7.10%); notably, this PCE value was obtained without the use of additives or thermal treatments. To our knowledge, the PCE over 7% is a significantly powerful value among rhodanine-based small molecule BHJ solar cells without additives or thermal treatments.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Perovskite Materials and Applications · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

POSTECH Organic Electronics Laboratory, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea

Funding

National Research Foundation of Korea

References (52)

Show source-provided references
1. 10.1021/cr050149z10.1021/cr050149z ↗
2. 10.1038/nenergy.2015.2710.1038/nenergy.2015.27 ↗
3. 10.1021/cr900182s10.1021/cr900182s ↗
4. 10.1039/c4tc00187g10.1039/c4tc00187g ↗
5. 10.1039/C4CP00077C10.1039/C4CP00077C ↗
6. 10.1038/ncomms629310.1038/ncomms6293 ↗
7. 10.1016/S1369-7021(13)70013-010.1016/S1369-7021(13)70013-0 ↗
8. 10.1038/nphoton.2014.26910.1038/nphoton.2014.269 ↗
9. 10.1039/C6CC03998G10.1039/C6CC03998G ↗
10. 10.1038/ncomms701310.1038/ncomms7013 ↗
11. 10.1002/anie.20110232610.1002/anie.201102326 ↗
12. 10.1002/adma.20130238910.1002/adma.201302389 ↗
13. 10.1002/adma.20120112710.1002/adma.201201127 ↗
14. 10.1021/jacs.5b0374010.1021/jacs.5b03740 ↗
15. 10.1002/adma.20150564510.1002/adma.201505645 ↗
16. 10.1039/C4TA03745F10.1039/C4TA03745F ↗
17. 10.1021/ja403318y10.1021/ja403318y ↗
18. 10.1039/C5TA08932H10.1039/C5TA08932H ↗
19. 10.1021/am501659u10.1021/am501659u ↗
20. 10.1021/acs.chemmater.5b0433910.1021/acs.chemmater.5b04339 ↗
21. 10.1002/chem.20130044510.1002/chem.201300445 ↗
22. 10.1021/acs.macromol.5b0051410.1021/acs.macromol.5b00514 ↗
23. 10.1039/C5CC03815D10.1039/C5CC03815D ↗
24. 10.1002/adma.20150381510.1002/adma.201503815 ↗
25. 10.1021/acs.chemmater.5b0388910.1021/acs.chemmater.5b03889 ↗
26. 10.1021/acs.chemmater.5b0261610.1021/acs.chemmater.5b02616 ↗
27. 10.1016/j.orgel.2015.10.00610.1016/j.orgel.2015.10.006 ↗
28. 10.1021/acs.chemmater.6b0176310.1021/acs.chemmater.6b01763 ↗
29. 10.1016/j.orgel.2015.12.02210.1016/j.orgel.2015.12.022 ↗
30. 10.1016/j.orgel.2015.01.01410.1016/j.orgel.2015.01.014 ↗
31. 10.1002/adma.20150339510.1002/adma.201503395 ↗
32. 10.1002/adma.20150064710.1002/adma.201500647 ↗
33. 10.1021/ja513189710.1021/ja5131897 ↗
34. 10.1002/adma.20150381510.1002/adma.201503815 ↗
35. 10.1021/acs.chemmater.5b0261610.1021/acs.chemmater.5b02616 ↗
36. 10.1002/aelm.20160006110.1002/aelm.201600061 ↗
37. 10.1021/ja900772210.1021/ja9007722 ↗
38. 10.1063/1.493746910.1063/1.4937469 ↗
39. 10.1039/B510618B10.1039/B510618B ↗
40. 10.1021/cr400353v10.1021/cr400353v ↗
41. 10.1039/C6TC01458E10.1039/C6TC01458E ↗
42. 10.1016/j.orgel.2016.04.01010.1016/j.orgel.2016.04.010 ↗
43. 10.1002/adma.20130418710.1002/adma.201304187 ↗
44. 10.1039/c2ee22056c10.1039/c2ee22056c ↗
45. 10.1002/aenm.20150257910.1002/aenm.201502579 ↗
46. 10.1039/C6NR00775A10.1039/C6NR00775A ↗
47. 10.1002/aenm.20140204410.1002/aenm.201402044 ↗
48. 10.1002/adma.20150401410.1002/adma.201504014 ↗
49. 10.1039/C5TA10430K10.1039/C5TA10430K ↗
50. 10.1039/C4EE03664F10.1039/C4EE03664F ↗
51. 10.1063/1.491358910.1063/1.4913589 ↗
52. 10.1038/nphoton.2015.910.1038/nphoton.2015.9 ↗