Tunable Key-Size Physical Unclonable Functions Based on Phase Segregation in Mixed Halide Perovskites

Optical physical unclonable functions (PUFs) have been considered as an effective tool for anti-counterfeiting owing to the uncontrollable manufacturing process and excellent resistance to machine-learning attacks. However, most optical PUFs exhibit fixed challenge-response pairs and static encoding structures after they are manufactured, which significantly impedes the actual development. Herein, we propose a tunable key-size PUF based on reversible phase segregation in mixed halide perovskites with uncontrollable Br/I ratios under variable power densities. The basic performance of encryption keys of low and high power density was evaluated and indicated a high degree of uniformity, uniqueness, and readout repeatability. Merging the binary keys of low and high power density, tunable key-size PUF is realized with higher security. The proposed tunable key-size PUF offers new insights into the development of dynamic-structure PUFs and demonstrates a novel scheme for achieving higher security of anti-counterfeiting and authentication.