journal article·2020-07-29

Cesium Acetate-Induced Interfacial Compositional Change and Graded Band Level in MAPbI3 Perovskite Solar Cells

Ajay Kumar Jena, Ayumi Ishii, Zhanglin Guo, Muhammad Akmal Kamarudin, Shuzi Hayase, Tsutomu Miyasaka

ACS Applied Materials & Interfaces· Volume 12· Issue 30
Publisher page

Abstract

Compositional engineering and interfacial modifications have played pivotal roles in the accomplishment of high-efficiency perovskite solar cells (PSCs). Different interfaces in the PSCs influence the performance remarkably either by altering the crystallization of the active material or shifting the energy levels or improving the electrical contact. This work reports how a thin layer of cesium acetate on the TiO2 electron transport layer (ETL) induces generation of a PbI2-rich methylammonium lead iodide (MAPbI3) composition at the ETL/MAPbI3 interface, which downshifts the conduction band level of MAPbI3 to create an energy level gradient favorable for carrier collection, resulting in higher photocurrent, fill factor, and overall power conversion efficiency.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Toin University of Yokohama, 1614 Kurogane-cho, Aoba, Yokohama 225-8503, Japan

The University of Electro-Communications, 1-5-1 Chofugaoka, Chofu 182-8585, Tokyo

Funding

Japan Society for the Promotion of Science

References (42)

Show source-provided references
1. 10.1021/ja809598r10.1021/ja809598r ↗
2. 10.1021/acs.chemrev.8b0053910.1021/acs.chemrev.8b00539 ↗
3. NREL. Best Research-cell efficiency Chart. https://www.nrel.gov/pv/cell-efficiency.html (Accessed on 2020-03-03)
4. 10.1002/adma.20180682310.1002/adma.201806823 ↗
5. 10.1021/acsaem.7b0006510.1021/acsaem.7b00065 ↗
6. 10.1002/solr.20190025710.1002/solr.201900257 ↗
7. 10.1002/aenm.20170062310.1002/aenm.201700623 ↗
8. 10.1002/admi.20190146910.1002/admi.201901469 ↗
9. 10.1038/nature1413310.1038/nature14133 ↗
10. 10.1039/c3ee43822h10.1039/c3ee43822h ↗
11. 10.1021/jz500679710.1021/jz5006797 ↗
12. 10.1039/c8ta04120b10.1039/c8ta04120b ↗
13. 10.1002/aenm.20170067710.1002/aenm.201700677 ↗
14. 10.1038/s41566-019-0398-210.1038/s41566-019-0398-2 ↗
15. 10.1002/admi.20190158410.1002/admi.201901584 ↗
16. 10.1038/s41467-019-10985-510.1038/s41467-019-10985-5 ↗
17. 10.1021/acsami.8b1061610.1021/acsami.8b10616 ↗
18. 10.1016/j.trechm.2019.11.00210.1016/j.trechm.2019.11.002 ↗
19. 10.1021/acssuschemeng.8b0658010.1021/acssuschemeng.8b06580 ↗
20. 10.1021/acsami.9b2348510.1021/acsami.9b23485 ↗
21. 10.1039/c8ta05291c10.1039/c8ta05291c ↗
22. 10.1002/pssa.20190049110.1002/pssa.201900491 ↗
23. 10.1016/j.orgel.2018.08.03910.1016/j.orgel.2018.08.039 ↗
24. 10.1002/aenm.20180039910.1002/aenm.201800399 ↗
25. 10.1016/j.jallcom.2019.02.02710.1016/j.jallcom.2019.02.027 ↗
26. 10.1021/acs.jpcc.7b0953710.1021/acs.jpcc.7b09537 ↗
27. 10.1039/c4ra08565e10.1039/c4ra08565e ↗
28. 10.1016/j.solmat.2019.11011010.1016/j.solmat.2019.110110 ↗
29. 10.1016/j.mtchem.2019.07.00110.1016/j.mtchem.2019.07.001 ↗
30. 10.1021/acsami.8b1006210.1021/acsami.8b10062 ↗
31. 10.1021/jp500449z10.1021/jp500449z ↗
32. 10.1016/j.solmat.2017.08.03210.1016/j.solmat.2017.08.032 ↗
33. 10.1016/j.solener.2016.07.01910.1016/j.solener.2016.07.019 ↗
34. 10.1021/acsami.8b1635810.1021/acsami.8b16358 ↗
35. 10.1063/1.513130010.1063/1.5131300 ↗
36. 10.1016/j.orgel.2019.10558310.1016/j.orgel.2019.105583 ↗
37. 10.1039/c6ra16839f10.1039/c6ra16839f ↗
38. 10.1002/aenm.20190323110.1002/aenm.201903231 ↗
39. 10.1021/acsami.6b1268310.1021/acsami.6b12683 ↗
40. 10.1021/acsami.9b2040210.1021/acsami.9b20402 ↗
41. 10.1063/1.489905110.1063/1.4899051 ↗
42. 10.1063/1.492255410.1063/1.4922554 ↗