journal article·2018-09-26

Enhancement of Switching Characteristic for p-Type Oxide Semiconductors Using Hypochlorous Acid

Tae Soo Jung, Heesoo Lee, Sung Pyo Park, Hee Jun Kim, Jin Hyeok Lee, Dongwoo Kim, Hyun Jae Kim

ACS Applied Materials & Interfaces· Volume 10· Issue 38
Publisher page

Abstract

We explored the effects of hypochlorous acid (HClO) oxidation on p-type oxide semiconductors. HClO generates oxygen radicals (O·) (strong reactive oxygen species) that affect the chemical state of p-type copper oxide (CuOx) thin films by reacting with CuOx. On robust oxidation by HClO, the numbers of Cu–O bonds increased and the numbers of copper vacancies serving as hole carriers decreased. In the modified CuOx thin-film transistors (TFTs), switching was evident. The subthreshold swing was 0.70 V/dec, the on-/off-current ratio was 4.86 × 104, and the field effect mobility was 2.83 × 10–3 cm2/V·s. Pristine CuOx TFTs did not exhibit switching.
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Research context

OpenAlex topics: Copper-based nanomaterials and applications · Thin-Film Transistor Technologies · ZnO doping and properties

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Affiliations

School of Electrical and Electronic Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Republic of Korea

Funding

LG Display · National Research Foundation of Korea

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