DataVXACS Applied Materials & InterfacesPaper
journal article·2018-01-31

Wafer-Scale Ultrathin Two-Dimensional Conjugated Microporous Polymers: Preparation and Application in Heterostructure Devices

Zhengdong Liu, Mengya Song, Shang Ju, Xiao Huang, Xiangjing Wang, Xiaotong Shi, Ya Zhu, Zhan Wang, Jie Chen, Hai Li, Yingchun Cheng, Linghai Xie, Juqing Liu, Wei Huang

ACS Applied Materials & Interfaces· Volume 10· Issue 4
Publisher page
Source abstract

Abstract

In this work, we report a universal surface-assisted oxidative polymerization strategy for wafer-scale fabrication of ultrathin two-dimensional conjugated microporous polymers (2D CMPs) on arbitrary substrates under ambient conditions. Three kinds of 2D CMPs with average thickness of 1.5–3.6 nm were prepared on SiO 2 /Si substrates by using carbazole based monomers. Moreover, 2D CMPs can be grown on reduced graphene oxide (rGO) substrate to construct large-area 2D CMP/rGO heterostructure. As a proof-of-concept demonstration, an organic vertical field-effect transistor based on 2D CMP/rGO heterostructures was fabricated, which exhibited typical p-type behavior with high reproducibility and on/off current ratio. Most importantly, the direct growth of large-area 2D CMPs on arbitrary substrates is compatible with the conventional processes in the semiconductor industry, and therefore is expected to expedite the development of 2D CMPs as building blocks for construction of practical electronic devices.
Source: openalex_inverted_index · Quality: baseline

Research context

PolymersNanomaterialsElectronic materials

OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Luminescence and Fluorescent Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, China

Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), SICAM, Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China

Shaanxi Institute of Flexible Electronics (SIFE), Northwestern Polytechnical University (NPU), 127 West Youyi Road, Xi’an 710072, China

Funding

Ministry of Science and Technology of the People's Republic of China · China Postdoctoral Science Foundation · Natural Science Foundation of Jiangsu Province · National Natural Science Foundation of China · Jiangsu Province

References (47)

Show source-provided references
1. 10.1021/cr300263a10.1021/cr300263a ↗
2. 10.1038/nnano.2014.20710.1038/nnano.2014.207 ↗
3. 10.1039/C4CS00399C10.1039/C4CS00399C ↗
4. 10.1038/nchem.162810.1038/nchem.1628 ↗
5. 10.1039/C5CC10283A10.1039/C5CC10283A ↗
6. 10.1038/nature1276310.1038/nature12763 ↗
7. 10.1038/nature1441710.1038/nature14417 ↗
8. 10.1126/science.125226810.1126/science.1252268 ↗
9. 10.1038/nmat271110.1038/nmat2711 ↗
10. 10.1038/nmat481510.1038/nmat4815 ↗
11. 10.1038/nchem.200710.1038/nchem.2007 ↗
12. 10.1002/adma.20130470510.1002/adma.201304705 ↗
13. 10.1021/ja512018j10.1021/ja512018j ↗
14. 10.1002/anie.20070159510.1002/anie.200701595 ↗
15. 10.1126/science.116542910.1126/science.1165429 ↗
16. 10.1038/ncomms684210.1038/ncomms6842 ↗
17. 10.1021/ja408355p10.1021/ja408355p ↗
18. 10.1039/C5NR06825H10.1039/C5NR06825H ↗
19. 10.1038/nnano.2007.34610.1038/nnano.2007.346 ↗
20. 10.1038/nchem.124210.1038/nchem.1242 ↗
21. 10.1039/c3sc50800e10.1039/c3sc50800e ↗
22. 10.1021/nn200393q10.1021/nn200393q ↗
23. 10.1002/anie.20140027310.1002/anie.201400273 ↗
24. 10.1002/adma.20130531710.1002/adma.201305317 ↗
25. 10.1038/ncomms229110.1038/ncomms2291 ↗
26. 10.1021/ja108628r10.1021/ja108628r ↗
27. 10.1021/ja805342n10.1021/ja805342n ↗
28. 10.1002/anie.20150847310.1002/anie.201508473 ↗
29. 10.1038/ncomms1346110.1038/ncomms13461 ↗
30. 10.1002/marc.20040065710.1002/marc.200400657 ↗
31. 10.1021/acsnano.5b0504010.1021/acsnano.5b05040 ↗
32. 10.1002/anie.20170027110.1002/anie.201700271 ↗
33. 10.1021/ja300438w10.1021/ja300438w ↗
34. 10.1002/adma.20130083910.1002/adma.201300839 ↗
35. 10.1126/science.121846110.1126/science.1218461 ↗
36. 10.1038/ncomms616210.1038/ncomms6162 ↗
37. Lin Z. · 2D Mater. · 2016 · 3 · 04200110.1088/2053-1583/3/4/042001 ↗
38. 10.1021/ma011911b10.1021/ma011911b ↗
39. 10.1016/j.progpolymsci.2013.09.00510.1016/j.progpolymsci.2013.09.005 ↗
40. 10.1016/j.progpolymsci.2012.02.00310.1016/j.progpolymsci.2012.02.003 ↗
41. 10.1039/b915995a10.1039/b915995a ↗
42. 10.1002/adma.20140272610.1002/adma.201402726 ↗
43. 10.1038/nmat259410.1038/nmat2594 ↗
44. 10.1038/nmat130910.1038/nmat1309 ↗
45. 10.1038/ncomms847810.1038/ncomms8478 ↗
46. 10.1126/science.122052710.1126/science.1220527 ↗
47. 10.1039/c1py00203a10.1039/c1py00203a ↗