A Wide Bandgap Polymer Donor Composed of Benzodithiophene and Oxime-Substituted Thiophene for High-Performance Organic Solar Cells

Oxime-substituted thiophene (TO) is used as an acceptor (A) unit to copolymerize with the benzodithiophene (BDT) donor (D) unit to form a novel D–A polymer donor, PBDTTO, which has a low-lying highest occupied molecular orbital energy level (EHOMO) of −5.60 eV and a wide bandgap of 2.03 eV, forming complementary absorption and matching energy levels with the narrow bandgap nonfullerene acceptors. Organic solar cells using PBDTTO and Y6 as the donor and acceptor, respectively, exhibited a JSC of 27.03 mA cm–2, a VOC of 0.83 V, and a fill factor of 0.59, reaching a high power conversion efficiency of 13.29%. The unencapsulated devices show good long-term stability in ambient air. Compared with the acceptor monomers used in other high-performance BDT-based D–A polymer donors, which are synthesized tediously in low yields, the TO acceptor monomer can be conveniently synthesized in only two steps with a high overall yield of 70%. These results demonstrate that TO unit can be used as a promising acceptor unit for developing BDT-based D–A polymer donors at low cost while maintaining high photovoltaic performance.