Ultrasensitive Fiber-Based ZnO Nanowire Network Ultraviolet Photodetector Enabled by the Synergism between Interface and Surface Gating Effects

A flexible UV photodetector with a high on/off ratio is extremely important for environmental sensing, optical communication, and flexible optoelectronic devices. In this work, a flexible fiber-based UV photodetector with an ultrahigh on/off ratio is developed by utilizing the synergism between interface and surface gating effects on a ZnO nanowire network structure. The synergism between two gating effects is realized by the interplay between surface band bending and the Fermi level through the nanowire network structure, which is proved through the control experiments between the ZnO micro/nanowire photodetector and micro/nanowire junction photodetector, and the corresponding Kelvin probe force microscopy (KPFM) measurements. The on/off ratio of the fiber-based ZnO nanowire network UV photodetector reaches 1.98 × 10 8 when illuminated by 1.0 mW cm –2 UV light, which is 20 times larger than the largest reported result under the same UV illumination. This new UV sensor also has a high resolution to UV light intensity change in the nW cm –2 range. Furthermore, when the fiber-based photodetector is curved, it still shows excellent performance as above. This work gives a new effective route for the development of a high-performance UV photodetector or other optoelectronic detection devices.