journal article·2014-08-27

Electrodeposited ZnO—Nanowire/Cu2O Photovoltaic Device with Highly Resistive ZnO Intermediate Layer

Masanobu Izaki, Takayuki Ohta, Misaki Kondo, Toshiaki Takahashi, Fariza Binti Mohamad, Mohd Zamzuri, Junji Sasano, Tsutomu Shinagawa, Thierry Pauporté

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Abstract

Cl-doped ZnO-nanowire (Cl:ZnO-nws)/Cu2O photovoltaic devices were prepared by electrodeposition in aqueous solutions, and the effects of the insertion of the highly resistive ZnO (i-ZnO) layer has been demonstrated by an improvement of the photovoltaic performance. The Cl:ZnO-nws and i-ZnO layer were prepared by electrodeposition in a zinc chloride aqueous solution with saturated molecular oxygen and simple zinc nitrate aqueous solution, respectively. The i-ZnO layer was directly deposited on the Cl:ZnO-nws and suppressed the electrodeposition of the Cu2O layer on the Cl:ZnO-nws. The insertion of the i-ZnO layer between the Cl:ZnO-nws and Cu2O layers induced an improvement in the photovoltaic performance from 0.40 to 1.26% with a 0.35 V open circuit voltage, 7.1 mA·cm(-2) short circuit current density, and 0.52 fill factor due to the reduction of the recombination loss.
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Research context

OpenAlex topics: Copper-based nanomaterials and applications · ZnO doping and properties · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Graduate School of Engineering, Toyohashi University of Technology, Toyohashi, Aichi 441-8580, Japan

Faculty of Electrical & Electronic Engineering, Universiti Tun Hussein Onn Malaysia, 86400 Parit Raja, Batu Pahat, Johor Malaysia

Electronics Materials Department, Osaka Municipal Technical Research Institute, Osaka, 536-8553, Japan

Institut de Recherche de Chimie Paris, CNRS − Chimie ParisTech, UMR8247, 11 rue Pierre et Marie Curie, Paris75005, France

Funding

Japan Society for the Promotion of Science · New Energy and Industrial Technology Development Organization · Amano Industrial Research Institute Foundation

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