journal article·2016-12-21

Tellurophene-Based N-type Copolymers for Photovoltaic Applications

Lei Lv, Xiaofen Wang, Xinlong Wang, Lei Yang, Tao Dong, Zhou Yang, Hui Huang

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Abstract

Novel tellurophene-based n-type copolymers are synthesized and characterized with thermal analysis, electrochemistry, optical spectroscopy, and DFT calculations. The copolymers demonstrate reversible interactions with bromine. Through tuning of the building blocks and alkyl chains together with device engineering, the maximum power conversion efficiency of all-polymer solar cells improves from 2.8 to 4.3%, which is supported by photoluminescence, atomic force microscopy, transmission electron microscopy, the space charge limit current method, and exciton dynamic studies. These results suggest that tellurophene-based n-type copolymers are promising electron acceptors for organic solar cells and potential sensor materials for bromine detection.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Materials Science and Optoelectronic Technology & CAS Key Laboratory of Vacuum Physics, University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Beijing Key Laboratory of Functional Materials for Molecular & Structure Construction, School of Materials Science and Engineering, University of Science and Technology—Beijing, Beijing 100083, P. R. China

Funding

Natural Science Foundation of Beijing Municipality · National Natural Science Foundation of China · Chinese Academy of Sciences

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