Effect of the Incorporation of a Low-Band-Gap Small Molecule in a Conjugated Vinylene Copolymer: PCBM Blend for Organic Photovoltaic Devices

The effect of the incorporation of a low-band-gap small-molecule BTD-TNP on the photovoltaic properties of vinylene copolymer P:PCBM bulk heterojunction solar cells has been investigated. The introduction of this small molecule increases both the short-circuit photocurrent and the overall power conversion efficiency of the photovoltaic device. The incident photon-to-current efficiency (IPCE) of the device based on P:PCBM:BTD-TNP shows two distinct bands, which correspond to the absorption bands of P:PCBM and BTD-TNP. Furthermore, it was found that the IPCE of the device has also been enhanced even at the wavelengths corresponding to the absorption band of P:PCBM, when the thermally annealed blend was used in the device. This indicates that the excitons that are generated in copolymer P are dissociated into charge carriers more effectively in the presence of the BTD-TNP small molecule at the copolymer P:PCBM interface by energy transfer from P to the small molecule. Therefore, we conclude that the BTD-TNP small molecule acts as light-harvesting photosensitizer and also provides a path for the generated exciton in copolymer P toward the P:PCBM interface for efficient charge separation. The overall power conversion efficiency for the P:PCBM:BTD-TNP photovoltaic device is about 1.27%, which has been further enhanced up to 2.6%, when a thermally annealed blend layer is used.