Facile Fabrication of Highly Conductive, Ultrasmooth, and Flexible Silver Nanowire Electrode for Organic Optoelectronic Devices

So far, one of the fundamental limitations of silver nanowires (Ag NWs) is the high contact resistance among their junctions. Moreover, a rough surface due to its random arrangement is inevitable to electrical short when the nanowire-based electronics is driving. To improve the contact resistance, we suggest that the particle shape nanocrystals are intentionally reduced at the junctions by a localized joule-heat reduction approach from the silver ions. Via localized reductions, the reduced nanoparticles effectively weld the junction’s areas, resulting in a 19% decrease in sheet resistance to 9.9 Ω sq–1. Besides, the nanowires are embedded into a polyamide film with gentle hot pressing. Consequently, the roughness was considerably dropped so that it was successful to demonstrate organic light-emitting diodes (OLEDs) with nanowires, which was beneficial to be laminated with OLEDs under the low temperature. The experimental results show that the Ag NW-embedded films reach 10.9 Ω sq–1 of the sheet resistance at 92% transmittance and the roughness was only 1.92 nm.