journal article·2018-08-29

Ionogel/Copper Grid Composites for High-Performance, Ultra-Stable Flexible Transparent Electrodes

Li Chang, Xiqi Zhang, Yi Ding, Hongliang Liu, Mingzhu Liu, Lei Jiang

ACS Applied Materials & Interfaces· Volume 10· Issue 34
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Abstract

Production of high-performance and stable low-cost copper (Cu)-based flexible transparent electrodes (FTEs) is urgently needed for the development of new-generation flexible optoelectronic devices, but it still remains challenging. Herein, we developed a facile approach to fabricate high-performance, ultra-stable Cu grid (CuG)-based FTEs by UV lithography-assisted electroless deposition of patterned Cu on flexible polyethylene terephthalate (PET), which is then encapsulated by a thin poly(1-vinyl-3-ethylimidazolium bis(trifluoromethanesulfonyl)imide) (P[VEIM][NTf2]) ionogel layer to improve the mechanical flexibility and stability. The as-prepared composite FTE (ionogel/CuG@PET) exhibits a sheet resistance of 10.9 Ω sq–1 and optical transmittance of 90% at 550 nm. Introduction of the thin uniform P[VEIM][NTf2] ionogel nanofilm by virtue of the superwettability of the Cu layer endows the electrode with excellent mechanical flexibility and stability. This new high-performance Cu-based FTE should be an attractive alternative to indium tin oxide for practical optoelectrical applications.
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Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Nanomaterials and Printing Technologies · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province and Department of Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Organic Solid, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Funding

State Administration of Foreign Experts Affairs · Ministry of Education of the People's Republic of China · Ministry of Science and Technology of the People's Republic of China · Youth Innovation Promotion Association of the Chinese Academy of Sciences · National Natural Science Foundation of China · Chinese Academy of Sciences

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