Inverse Growth of Large-Grain-Size and Stable Inorganic Perovskite Micronanowire Photodetectors

Control of forward and inverse reactions between perovskites and precursor materials is key to attaining high-quality perovskite materials. Many techniques focus on synthesizing nanostructured CsPbX₃ materials (e.g., nanowires) via a forward reaction (CsX + PbX₂ → CsPbX₃). However, low solubility of inorganic perovskites and complex phase transition make it difficult to realize the precise control of composition and length of nanowires using the conventional forward approach. Herein, we report the self-assembly inverse growth of CsPbBr₃ micronanowires (MWs) (CsPb₂Br₅ → CsPbBr₃ + PbBr₂↑) by controlling phase transition from CsPb₂Br₅ to CsPbBr₃. The two-dimensional (2D) structure of CsPb₂Br₅ serves as nucleation sites to induce initial CsPbBr₃ MW growth. Also, phase transition allows crystal rearrangement and slows down crystal growth, which facilitates the MW growth of CsPbBr₃ crystals along the 2D planes of CsPb₂Br₅. A CsPbBr₃ MW photodetector constructed based on the inverse growth shows a high responsivity of 6.44 A W^-1 and detectivity of ∼10¹² Jones. Large grain size, high crystallinity, and large thickness can effectively alleviate decomposition/degradation of perovskites, which leads to storage stability for over 60 days in humid environment (relative humidity = 45%) and operational stability for over 3000 min under illumination (wavelength = 400 nm, light intensity = 20.06 mW cm^-2).