journal article·2021-05-19

High Energy Performance Ferroelectric (Ba,Sr)(Zr,Ti)O3 Film Capacitors Integrated on Si at 400 °C

Kun Wang, Yuan Zhang, Sixu Wang, Yu-Yao Zhao, Hongbo Cheng, Qian Li, Xiangli Zhong, Jun Ouyang

ACS Applied Materials & Interfaces· Volume 13· Issue 19
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Abstract

BaTiO3-based ferroelectrics have been extensively studied due to their large dielectric constants and a high saturated polarization, which have the potential to store or supply electricity of very high energy and power densities. In order to further improve the energy efficiency η and the recyclable energy density Wrec, an A, B-site co-doped (Ba0.95,Sr0.05)(Zr0.2,Ti0.8)O3 ceramic target was used for sputter deposition of film capacitor structures on Si. This film composition reduces the remnant polarization Pr, while the choice of a low-temperature, templated sputtering process facilitates the formation of high-density arrays of columnar nanograins (average diameter d ∼20 nm) and grain boundary dead layers. This self-assembled nanostructure further delays the saturation of the electric polarization, leading to a high energy density Wrec of ∼148 J/cm3 and a high energy efficiency η of ∼90%. Moreover, the (Ba0.95,Sr0.05)(Zr0.2,Ti0.8)O3 film capacitors retain their high energy storage performance in a broad range of working temperature (−175–300 °C) and operating frequency (1 Hz–20 kHz). They are also fatigue-free after up to 2 × 109 switching cycles. Our work provides a new method and a cost-effective processing route for the creation and integration of high-performance dielectric capacitors for energy storage applications.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Dielectric materials and actuators · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory for Liquid-Solid Structure Evolution and Processing of Materials (Ministry of Education), School of Materials Science and Engineering, Shandong University, Jinan 250061, China

Institute of Advanced Energy Materials and Chemistry, Jinan Engineering Laboratory for Multi-scale Functional Materials, Shandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China

Shenzhen Key Laboratory of Nanobiomechanics, Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, China

State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

School of Materials Science and Engineering, Xiangtan University, Xiangtan, Hunan 411105, China

Funding

Qilu University of Technology · National Natural Science Foundation of China · Shandong Academy of Sciences · Independent Innovation Foundation of Shandong University · State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University · Suzhou City

References (68)

Show source-provided references
1. 10.1126/science.112779810.1126/science.1127798 ↗
2. 10.1038/ncomms384510.1038/ncomms3845 ↗
3. 10.1016/j.nanoen.2018.07.00710.1016/j.nanoen.2018.07.007 ↗
4. 10.1126/science.aaw810910.1126/science.aaw8109 ↗
5. 10.1016/j.jeurceramsoc.2020.06.03810.1016/j.jeurceramsoc.2020.06.038 ↗
6. 10.1038/s41467-017-02040-y10.1038/s41467-017-02040-y ↗
7. 10.1016/j.nanoen.2020.10539010.1016/j.nanoen.2020.105390 ↗
8. 10.1002/aenm.20200177810.1002/aenm.202001778 ↗
9. 10.1016/j.nanoen.2018.12.05610.1016/j.nanoen.2018.12.056 ↗
10. 10.1002/aenm.20180320410.1002/aenm.201803204 ↗
11. 10.1002/adfm.20180719610.1002/adfm.201807196 ↗
12. Gonzalez, P.; Guo, B.; Severi, S.; De Meyer, K.; Witvrouw, A. A CMOS Compatible Polycrystalline Silicon-Germanium Based Piezoresistive Pressure Sensor. Transducers 2011-IEEE 16th International Solid-State Sensors, Actuators and Microsystems Conference, Beijing, China, June 5–9, 2011; pp 1076–1079.10.1109/TRANSDUCERS.2011.5969178 ↗
13. 10.1109/16.90274110.1109/16.902741 ↗
14. 10.1007/s10854-016-5528-810.1007/s10854-016-5528-8 ↗
15. 10.1063/1.477201610.1063/1.4772016 ↗
16. 10.1016/j.actamat.2014.10.06310.1016/j.actamat.2014.10.063 ↗
17. 10.1016/j.actamat.2015.01.01510.1016/j.actamat.2015.01.015 ↗
18. 10.1063/1.480731510.1063/1.4807315 ↗
19. 10.1016/j.jeurceramsoc.2006.02.00110.1016/j.jeurceramsoc.2006.02.001 ↗
20. 10.1021/acsami.0c0715510.1021/acsami.0c07155 ↗
21. Ouyang J. · 2019
22. 10.1016/j.ceramint.2016.03.13710.1016/j.ceramint.2016.03.137 ↗
23. 10.1016/j.ceramint.2015.08.09810.1016/j.ceramint.2015.08.098 ↗
24. 10.1016/j.actamat.2020.09.02210.1016/j.actamat.2020.09.022 ↗
25. 10.1016/j.ceramint.2013.02.06010.1016/j.ceramint.2013.02.060 ↗
26. 10.1007/s10854-019-02299-510.1007/s10854-019-02299-5 ↗
27. 10.1016/j.jsamd.2019.12.00110.1016/j.jsamd.2019.12.001 ↗
28. 10.1111/jace.1277310.1111/jace.12773 ↗
29. 10.1016/j.commatsci.2008.04.00110.1016/j.commatsci.2008.04.001 ↗
30. 10.1063/1.290821010.1063/1.2908210 ↗
31. 10.1126/science.110321810.1126/science.1103218 ↗
32. 10.1103/physrevlett.95.25760110.1103/physrevlett.95.257601 ↗
33. 10.1080/1058458970801569910.1080/10584589708015699 ↗
34. 10.1111/jace.1580310.1111/jace.15803 ↗
35. 10.1063/1.12700210.1063/1.127002 ↗
36. 10.1063/1.130853110.1063/1.1308531 ↗
37. 10.1109/ted.2003.81514110.1109/ted.2003.815141 ↗
38. 10.1111/j.1551-2916.2011.04740.x10.1111/j.1551-2916.2011.04740.x ↗
39. 10.1039/c8tc02819b10.1039/c8tc02819b ↗
40. 10.1021/am506247w10.1021/am506247w ↗
41. 10.1063/1.11311110.1063/1.113111 ↗
42. 10.1063/1.163175010.1063/1.1631750 ↗
43. 10.1063/1.494568310.1063/1.4945683 ↗
44. 10.1515/msp-2015-010710.1515/msp-2015-0107 ↗
45. 10.1021/acsami.0c0556010.1021/acsami.0c05560 ↗
46. 10.1002/aenm.20190422910.1002/aenm.201904229 ↗
47. 10.1002/aenm.20180394910.1002/aenm.201803949 ↗
48. 10.1007/BF0027533610.1007/BF00275336 ↗
49. 10.1111/jace.1700210.1111/jace.17002 ↗
50. 10.1063/1.489245410.1063/1.4892454 ↗
51. 10.1142/s2010135x1100014810.1142/s2010135x11000148 ↗
52. 10.1103/physrevb.70.02410710.1103/physrevb.70.024107 ↗
53. 10.1007/s00339-004-3096-x10.1007/s00339-004-3096-x ↗
54. 10.1088/0022-3727/37/5/01610.1088/0022-3727/37/5/016 ↗
55. 10.1063/1.136731810.1063/1.1367318 ↗
56. 10.1111/j.1551-2916.2007.01900.x10.1111/j.1551-2916.2007.01900.x ↗
57. 10.1111/j.1551-2916.2009.03311.x10.1111/j.1551-2916.2009.03311.x ↗
58. 10.1016/j.mset.2018.11.00510.1016/j.mset.2018.11.005 ↗
59. 10.1088/0022-3727/31/13/00610.1088/0022-3727/31/13/006 ↗
60. 10.1016/j.nanoen.2020.10486210.1016/j.nanoen.2020.104862 ↗
61. 10.1038/nature1464710.1038/nature14647 ↗
62. 10.1039/c7ta11109f10.1039/c7ta11109f ↗
63. 10.1063/1.236314310.1063/1.2363143 ↗
64. 10.1016/j.matchemphys.2010.06.03210.1016/j.matchemphys.2010.06.032 ↗
65. 10.1002/aenm.20140061010.1002/aenm.201400610 ↗
66. 10.1007/s10854-015-3025-010.1007/s10854-015-3025-0 ↗
67. 10.1021/acsami.5b0279010.1021/acsami.5b02790 ↗
68. 10.1002/adma.20160442710.1002/adma.201604427 ↗