journal article·2018-05-23

Molybdenum and Niobium Codoped B-Site-Ordered Double Perovskite Catalyst for Efficient Oxygen Evolution Reaction

Hainan Sun, Gao Chen, Jaka Sunarso, Jie Dai, Wei Zhou, Zongping Shao

ACS Applied Materials & Interfaces· Volume 10· Issue 20
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Abstract

An abundant, highly active, and durable oxygen evolution reaction (OER) electrocatalyst is an enabling component for a more sustainable energy future. We report, herein, a molybdenum and niobium codoped B-site-ordered double perovskite oxide with a compositional formula of Ba2CoMo0.5Nb0.5O6−δ (BCMN) as an active and robust catalyst for OER in an alkaline electrolyte. BCMN displayed a low overpotential of 445 mA at a current density of 10 mA cm–2disk. BCMN also showed long-term stability in an alkaline medium. This work hints toward the possibility of combining a codoping approach with double perovskite structure formation to achieve significant enhancement in the OER performance.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Fuel Cells and Related Materials · Advancements in Solid Oxide Fuel Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, P. R. China

Faculty of Engineering, Computing and Science, Swinburne University of Technology, Jalan Simpang Tiga, Kuching, Sarawak 93350, Malaysia

Department of Chemical Engineering, Curtin University, Perth, Western Australia 6845, Australia

Funding

Natural Science Foundation of Jiangsu Province · Government of Jiangsu Province · National Natural Science Foundation of China

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