journal article·2017-03-22

Continuous Size Tuning of Monodispersed ZnO Nanoparticles and Its Size Effect on the Performance of Perovskite Solar Cells

Rong Zhang, Chengbin Fei, Bo Li, Haoyu Fu, Jianjun Tian, Guozhong Cao

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Abstract

ZnO has been demonstrated to be a promising candidate to fabricate high efficiency perovskite solar cells (PSCs) in terms of its better electron extraction and transport properties. However, the inability of synthesis of ZnO nanoparticles (NPs) with minimal surface defects and agglomeration remains a great challenge hindering the fabrication of highly efficient PSCs. In this work, highly crystalline and agglomeration-free ZnO NPs with controlled size were synthesized through a facile solvothermal method. Such ZnO NPs were applied in the fabrication of meso-structured PSCs. The solar cells with ∼40 nm ZnO NPs exhibit the highest power conversion efficiency (PCE) of 15.92%. Steady-state and time-resolved photoluminescence measurements revealed the faster injection and lower charge recombination at the interface of ∼40 nm ZnO NPs and perovskite, resulting in significantly enhanced J SC and V OC .
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Research context

OpenAlex topics: Perovskite Materials and Applications · Quantum Dots Synthesis And Properties · Chalcogenide Semiconductor Thin Films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, National Center for Nanoscience and Technology (NCNST), Beijing 100083, China

Advanced Material and Technology Institute, University of Science and Technology, Beijing 100083, China

Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195-2120, United States

Funding

Program for New Century Excellent Talents in University · Ministry of Education of the People's Republic of China · China Postdoctoral Science Foundation · National Natural Science Foundation of China · Thousand Talents Program for Pioneer Researcher and his Innovation Team

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