journal article·2016-09-14

Efficiency-Enhanced Planar Perovskite Solar Cells via an Isopropanol/Ethanol Mixed Solvent Process

Peng Mao, Qing Zhou, Zhiwen Jin, Hui Li, Jizheng Wang

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Abstract

Solution processable perovskite solar cells traditionally employed isopropanol as the solvent of CH3NH3I in a two-step method. One of the largest issues of this technique is the uncontrollable morphology of the perovskite film. In this study, a homogeneous and dense PbI2 film was prepared by introducing DMSO as an additive into DMF and then reacting the mixture with CH3NH3I dissolved in an isopropanol/ethanol solvent to fabricate high-quality perovskite films. Results revealed that ethanol played a crucial role on morphology and components of perovskite films. When the ratio of isopropanol to ethanol was optimized, a power conversion efficiency of 15.76% was achieved, which was on average ∼50% higher than that of PSCs without DMSO and ethanol processing.
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Research context

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Chalcogenide Semiconductor Thin Films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

University of Chinese Academy of Science, 19 A Yuquan Road, Shijingshan District, Beijing 100049, China

Funding

Ministry of Science and Technology of the People's Republic of China · CAS-SAFEA International Partnership Program for Creative Research Teams · National Natural Science Foundation of China · Chinese Academy of Sciences

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