journal article·2021-09-01

Organic Persistent Luminescent Materials: Ultralong Room-Temperature Phosphorescence and Multicolor-Tunable Afterglow

Renjie Chen, Yan Guan, Hailong Wang, Yan Zhu, Xin Tan, Ping Wang, Xueye Wang, Xinghe Fan, He-Lou Xie

ACS Applied Materials & Interfaces· Volume 13· Issue 34
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Abstract

Organic persistent luminescent materials have attracted special attention due to their significant applications in optoelectronics, sensors, and security technology areas. In this work, a series of organic compounds (1-4) with twisted electron donor-acceptor structures are successfully designed and synthesized, and then the resultant compounds are dissolved in methyl methacrylate (MMA), and afterward, in situ polymerization realizes single-molecular organic room-temperature phosphorescent (RTP) materials (P1-P4). All RTP materials show long lifetime, especially P2 exhibits ultralong lifetime of 1.51 s. When the compounds are grown into single crystals, multicolor-tunable afterglow is obtained at different delay times due to the dual emission of phosphorescence and delayed fluorescence, which is promising to be applied in high-level anticounterfeiting.
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Research context

OpenAlex topics: Luminescence and Fluorescent Materials · Organic Light-Emitting Diodes Research · Molecular Sensors and Ion Detection

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Lab of Environment-friendly Chemistry and Application in Ministry of Education, and Key Laboratory of Advanced Functional Polymer Materials of Colleges, Universities of Hunan Province and College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105, China

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Polymer Chemistry and Physics of Ministry of Education, Center for Soft Matter Science and Engineering, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Funding

Natural Science Foundation of Hunan Province · Education Department of Hunan Province · National Natural Science Foundation of China · Scientific Research Foundation of Hunan Provincial Education Department

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