journal article·2019-05-01

Layered Thiazolo[5,4-d] Thiazole-Linked Conjugated Microporous Polymers with Heteroatom Adoption for Efficient Photocatalysis Application

Qi Huang, Liping Guo, Ning Wang, Xiang Zhu, Shangbin Jin, Bien Tan

ACS Applied Materials & Interfaces· Volume 11· Issue 17
Publisher page

Abstract

Conjugated microporous polymers (CMPs) with high surface areas, tunable building blocks, and fully conjugated structures have found important applications in optoelectronics. Here, we report a new series of CMPs with tunable band gaps by introducing thiazolo[5,4- d] thiazole as the linkage. Because they are synthetic polymers, the geometries and structures could be rationally designed. Their intrinsic wide visible-light absorption properties and layered architectures endow them with a promising photocatalytic performance. The role of geometries, surface areas, and morphologies of the CMPs in photocatalysis abilities is examined and discussed. The results indicate that geometries have a direct impact on the surface areas and morphologies of the CMPs and thus exert great influence on photocatalysis.
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Research context

OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road No. 1037, 430074 Wuhan, China

Department of Chemistry, Texas A&M University, 77840 College Station, United States

Funding

National Natural Science Foundation of China · Huazhong University of Science and Technology · China Postdoctoral Science Foundation · Ministry of Science and Technology of the People's Republic of China

References (41)

Show source-provided references
1. 10.1021/acs.macromol.5b0257210.1021/acs.macromol.5b02572 ↗
2. 10.1039/b707925g10.1039/b707925g ↗
3. 10.1039/c8cp00974k10.1039/c8cp00974k ↗
4. 10.1002/smll.20160038210.1002/smll.201600382 ↗
5. 10.1039/c1cs15172j10.1039/c1cs15172j ↗
6. 10.1002/celc.20140230710.1002/celc.201402307 ↗
7. 10.1021/acscatal.5b0099110.1021/acscatal.5b00991 ↗
8. 10.1039/c4cs00141a10.1039/c4cs00141a ↗
9. 10.1039/c6ra16539g10.1039/c6ra16539g ↗
10. 10.1039/c3cs60160a10.1039/c3cs60160a ↗
11. 10.1016/j.progpolymsci.2011.09.00210.1016/j.progpolymsci.2011.09.002 ↗
12. 10.1002/anie.20070159510.1002/anie.200701595 ↗
13. 10.1002/anie.20160737510.1002/anie.201607375 ↗
14. 10.1039/c6cc03536a10.1039/c6cc03536a ↗
15. 10.1039/c5ta03820k10.1039/c5ta03820k ↗
16. 10.1039/c3tc32363c10.1039/c3tc32363c ↗
17. 10.1002/adma.20150273510.1002/adma.201502735 ↗
18. 10.1002/advs.20170010110.1002/advs.201700101 ↗
19. 10.1002/macp.20170004910.1002/macp.201700049 ↗
20. 10.1039/c7nr00534b10.1039/c7nr00534b ↗
21. 10.1021/acscatal.8b0260710.1021/acscatal.8b02607 ↗
22. 10.1021/ja511552k10.1021/ja511552k ↗
23. 10.1039/c8ta04186e10.1039/c8ta04186e ↗
24. 10.1002/anie.20160353210.1002/anie.201603532 ↗
25. 10.1016/j.apcatb.2018.01.0710.1016/j.apcatb.2018.01.07 ↗
26. 10.1002/adma.20170242810.1002/adma.201702428 ↗
27. 10.1002/aenm.20180108410.1002/aenm.201801084 ↗
28. 10.1039/c6ta04711d10.1039/c6ta04711d ↗
29. 10.1038/ncomms950810.1038/ncomms9508 ↗
30. 10.1039/c7ta03776g10.1039/c7ta03776g ↗
31. 10.1016/j.jphotochem.2018.01.01610.1016/j.jphotochem.2018.01.016 ↗
32. 10.1016/j.jhazmat.2018.01.02710.1016/j.jhazmat.2018.01.027 ↗
33. 10.1039/c4cc07255c10.1039/c4cc07255c ↗
34. 10.1039/c5cp00081e10.1039/c5cp00081e ↗
35. 10.1002/adma.20130361110.1002/adma.201303611 ↗
36. 10.1039/c3cc45901b10.1039/c3cc45901b ↗
37. 10.1021/ja408243n10.1021/ja408243n ↗
38. 10.1038/nmat422010.1038/nmat4220 ↗
39. 10.1039/c4ra06658h10.1039/c4ra06658h ↗
40. 10.1039/b921692h10.1039/b921692h ↗
41. 10.1021/acs.langmuir.7b0019010.1021/acs.langmuir.7b00190 ↗