Alkyl Chain Length Dependence of the Field-Effect Mobility in Novel Anthracene Derivatives
Source abstract
Abstract
We report six asymmetric alkylated anthracene-based molecules with different alkyl side chain lengths for use in organic field-effect transistors (OFETs). Alkyl side chains can potentially improve the solubility and processability of anthracene derivatives. The crystallinity and charge mobility of the anthracene derivatives may be improved by optimizing the side chain length. The highest field-effect mobility of the devices prepared here was 0.55 cm(2)/(V s), for 2-(p-pentylphenylethynyl)anthracene (PPEA). The moderate side chain length appeared to be optimal for promoting self-organization among asymmetric anthracene derivatives in OFETs, and was certainly better than the short or long alkyl side chain lengths, as confirmed by X-ray diffraction measurements.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Organic Electronics and Photovoltaics · Organic Light-Emitting Diodes Research · Perovskite Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Materials Science & Engineering, Engineering Research Institute (ERI), Gyeongsang National University, Jinju 660-701, Republic of Korea
Polymer Research Institute, Department of Chemical Engineering, Pohang University of Science and Technology (POSTECH), Pohang 790-784, Republic of Korea
Department of Chemistry & Engineering Research Institute (ERI), Gyeongsang National University, Jinju 660-701, Republic of Korea
School of Chemical Engineering and Material Science, Chung-Ang University, Seoul 156-756, Republic of Korea
Funding
National Research Foundation of Korea · Ministry of Education, Science and Technology
References (62)
Show source-provided references
1. Zhang F. · J. Am. Chem. Soc. · 2013 · 135 · 233810.1021/ja311469y ↗
2. Kang I. · Adv. Mater. · 2013 · 25 · 52410.1002/adma.201202867 ↗
3. Uoyama H. · Nature · 2012 · 492 · 23410.1038/nature11687 ↗
4. So K. H. · Dyes Pigm. · 2012 · 92 · 60310.1016/j.dyepig.2011.04.017 ↗
5. Cha H. · Adv. Energy Mater. · 2013 · 3 · 101810.1002/aenm.201300078 ↗
6. Kim H. G. · J. Mater. Chem. · 2012 · 22 · 1770910.1039/c2jm32514d ↗
7. Chung D. S. · Opt. Lett. · 2013 · 38 · 281410.1364/OL.38.002814 ↗
8. Yiming W. · Nanotechnology · 2013 · 24 · 35520110.1088/0957-4484/24/35/355201 ↗
9. Afzali A. · J. Am. Chem. Soc. · 2002 · 124 · 881210.1021/ja0266621 ↗
10. Ito K. · Angew. Chem., Int. Ed. · 2003 · 42 · 115910.1002/anie.200390305 ↗
11. Dong H. · Chem. Commun. · 2010 · 46 · 521110.1039/c0cc00947d ↗
12. Marrocchi A. · Chem. Mater. · 2009 · 21 · 259210.1021/cm900734c ↗
13. Dost R. · Appl. Phys. Lett. · 2008 · 93 · 11350510.1063/1.2987425 ↗
14. Wu W. · Chem. Soc. Rev. · 2010 · 39 · 148910.1039/B813123F ↗
15. Anthony J. E. · Chem. Rev. · 2006 · 106 · 502810.1021/cr050966z ↗
16. Kim J. · J. Mater. Chem. C · 2013 · 1 · 127210.1039/C2TC00280A ↗
17. Lee B. · Phys. Rev. B · 2010 · 82 · 08530210.1103/PhysRevB.82.085302 ↗
18. Fan C.-L. · Org. Electron. · 2013 · 14 · 222810.1016/j.orgel.2013.05.031 ↗
19. Park S. · Org. Electron. · 2012 · 13 · 278610.1016/j.orgel.2012.08.025 ↗
20. Park J. H. · Org. Electron. · 2012 · 13 · 125010.1016/j.orgel.2012.04.001 ↗
21. Kim S.-o. · Adv. Funct. Mater. · 2011 · 21 · 161610.1002/adfm.201002367 ↗
22. Swartz C. R. · Org. Lett. · 2005 · 7 · 316310.1021/ol050872b ↗
23. Melucci M. · Chem. Mater. · 2013 · 25 · 66810.1021/cm303224a ↗
24. Tang Q. · Adv. Mater. · 2006 · 18 · 6510.1002/adma.200501654 ↗
25. Barlow S. · J. Phys. Chem. B · 2010 · 114 · 1439710.1021/jp100774r ↗
26. Tang W. · J. Mater. Chem. · 2010 · 20 · 149710.1039/b920112b ↗
27. Usta H. · J. Mater. Chem. · 2012 · 22 · 445910.1039/C1JM14713G ↗
28. An T. K. · Adv. Mater. · 2013 · 25 · 700310.1002/adma.201301438 ↗
29. Ye Q. · Chem. Mater. · 2014 · 26 · 404610.1021/cm501536p ↗
30. An T. K. · Sci. Adv. Mater. · 2013 · 5 · 132310.1166/sam.2013.1566 ↗
31. Desiraju G. R. · J. Chem. Soc., Chem. Commun. · 1989 · 62110.1039/c39890000621 ↗
32. Jang S. H. · Bull. Korean Chem. Soc. · 2012 · 33 · 54110.5012/bkcs.2012.33.2.541 ↗
33. Aleshin A. N. · Appl. Phys. Lett. · 2004 · 84 · 538310.1063/1.1767282 ↗
34. Murphy A. R. · Chem. Rev. · 2007 · 107 · 106610.1021/cr0501386 ↗
35. Zhang F. · Org. Electron. · 2013 · 14 · 88810.1016/j.orgel.2013.01.003 ↗
36. Yun H.-J. · J. Mater. Chem. · 2012 · 22 · 2492410.1039/c2jm34160c ↗
37. Mei J. · J. Am. Chem. Soc. · 2013 · 135 · 672410.1021/ja400881n ↗
38. Ito K. · Angew. Chem. · 2003 · 115 · 119110.1002/ange.200390276 ↗
39. Brocks G. · Phys. Rev. Lett. · 2004 · 93 · 14640510.1103/PhysRevLett.93.146405 ↗
40. Payne M. M. · J. Am. Chem. Soc. · 2005 · 127 · 498610.1021/ja042353u ↗
41. Zhao Q. · Adv. Mater. · 2008 · 20 · 486810.1002/adma.200800061 ↗
42. Kim H.-S. · Chem. Mater. · 2007 · 19 · 356110.1021/cm070053g ↗
43. Halik M. · Adv. Mater. · 2003 · 15 · 91710.1002/adma.200304654 ↗
44. Kitamura C. · Mol. Cryst. Liq. Cryst. · 2007 · 474 · 11910.1080/15421400701617350 ↗
45. Chen J. · J. Mater. Chem. · 2008 · 18 · 196110.1039/b717082c ↗
46. Nguyen T.-Q. · J. Phys. Chem. B · 2000 · 104 · 23710.1021/jp993190c ↗
47. An T. K. · Chem.—Eur. J. · 2013 · 19 · 1405210.1002/chem.201302588 ↗
48. Chen S. · J. Mater. Chem. C · 2014 · 2 · 218310.1039/C3TC32219J ↗
49. Lei T. · Chem. Mater. · 2013 · 26 · 59410.1021/cm4018776 ↗
50. Mei J. · Chem. Mater. · 2014 · 26 · 60410.1021/cm4020805 ↗
51. Zhang J. · J. Mater. Chem. C · 2013 · 1 · 320010.1039/c3tc30156g ↗
52. Kang I. · J. Am. Chem. Soc. · 2013 · 135 · 1489610.1021/ja405112s ↗
53. Pei J. · J. Mater. Chem. C · 2014 · 2 · 815210.1039/C4TC01369G ↗
54. An T. K. · Dyes Pigm. · 2013 · 96 · 75610.1016/j.dyepig.2012.11.018 ↗
55. Kim C. · Org. Electron. · 2010 · 11 · 136310.1016/j.orgel.2010.04.029 ↗
56. Spano F. C. · Annu. Rev. Phys. Chem. · 2006 · 57 · 21710.1146/annurev.physchem.57.032905.104557 ↗
57. Park J.-H. · Org. Electron. · 2010 · 11 · 82010.1016/j.orgel.2010.01.024 ↗
58. Hunter C. A. · J. Am. Chem. Soc. · 1990 · 112 · 552510.1021/ja00170a016 ↗
59. Tsuzuki S. · J. Am. Chem. Soc. · 2001 · 124 · 10410.1021/ja0105212 ↗
60. Jeong Y. J. · ACS Appl. Mater. Interfaces · 2014 · 6 · 681610.1021/am500618g ↗
61. Choi D. · ACS Appl. Mater. Interfaces · 2012 · 4 · 11710.1021/am201074n ↗
62. Amin A. Y. · J. Am. Chem. Soc. · 2012 · 134 · 1654810.1021/ja307802q ↗