journal article·2022-08-03

Oxidation of Spiro-OMeTAD in High-Efficiency Perovskite Solar Cells

Nabonswende Aida Nadege Ouedraogo, George Omololu Odunmbaku, Bing Guo, Shanshan Chen, Xiaoxue Lin, Tatyana Shumilova, Kuan Sun

ACS Applied Materials & Interfaces· Volume 14· Issue 30
Publisher page

Abstract

2,2',7,7'-Tetrakis(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD), as an organic small molecule material, is the most commonly employed hole transport material (HTM) in perovskite solar cells (PSCs) because of its excellent properties that result in high photovoltaic performances. However, the material still suffers from low conductivity, leading to the necessary use of dopants and oxidative processes to overcome this issue. The spiro-OMeTAD oxidation process is highlighted in this review, and the main parameters involved in the process have been studied. Furthermore, the best alternatives aiming to improve the spiro-OMeTAD electrical properties have been discussed. Lastly, this review concludes with suggestions and outlooks for further research directions.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Perovskite Materials and Applications · Conducting polymers and applications · Organic Electronics and Photovoltaics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

MOE Key Laboratory of Low-grade Energy Utilization Technologies and Systems, School of Energy & Power Engineering, Chongqing University, Chongqing 400044, China

Institute of Geology, FRC Komi Science Center, Ural Branch, Russian Academy of Sciences, Syktyvkar 167982, Russia

Funding

Ministry of Education of the People's Republic of China · Natural Science Foundation of Chongqing · National Natural Science Foundation of China · Chongqing Funds for Distinguished Young Scientists · Youth Talent Support Program of Chongqing

References (100+)

Show source-provided references
1. 10.1021/ja809598r10.1021/ja809598r ↗
2. 10.1016/j.materresbull.2021.11170010.1016/j.materresbull.2021.111700 ↗
3. 10.1039/C7EE00757D10.1039/C7EE00757D ↗
4. 10.1002/advs.20160026910.1002/advs.201600269 ↗
5. 10.1039/D0EE02164D10.1039/D0EE02164D ↗
6. 10.1016/j.omx.2021.10012210.1016/j.omx.2021.100122 ↗
7. 10.1016/j.nantod.2021.10115510.1016/j.nantod.2021.101155 ↗
8. Sahoo S. K. · 2018 · 1
9. 10.1002/admi.20210213710.1002/admi.202102137 ↗
10. 10.1038/nphoton.2014.28410.1038/nphoton.2014.284 ↗
11. 10.1126/science.124398210.1126/science.1243982 ↗
12. 10.1126/science.aaa576010.1126/science.aaa5760 ↗
13. 10.1063/1.489732910.1063/1.4897329 ↗
14. 10.1021/ic401215x10.1021/ic401215x ↗
15. 10.1002/adma.20130517210.1002/adma.201305172 ↗
16. 10.1038/s41586-018-0576-210.1038/s41586-018-0576-2 ↗
17. 10.1038/s41586-021-03997-z10.1038/s41586-021-03997-z ↗
18. 10.1021/acs.chemrev.0c0010710.1021/acs.chemrev.0c00107 ↗
19. 10.1038/s41586-021-03406-510.1038/s41586-021-03406-5 ↗
20. 10.1126/science.abc441710.1126/science.abc4417 ↗
21. 10.1126/science.abb716710.1126/science.abb7167 ↗
22. 10.1021/acsenergylett.1c0176310.1021/acsenergylett.1c01763 ↗
23. 10.1016/j.nanoen.2018.09.02310.1016/j.nanoen.2018.09.023 ↗
24. 10.1016/j.nanoen.2019.10424910.1016/j.nanoen.2019.104249 ↗
25. NREL Best Research Cell Efficiencies. National Renewable Energy Laboratory. https://www.nrel.gov/pv/cell-efficiency.html (accessed 2022-03-07).
26. 10.1039/D0SE00555J10.1039/D0SE00555J ↗
27. 10.1002/smll.20200408110.1002/smll.202004081 ↗
28. 10.1038/s41563-019-0478-110.1038/s41563-019-0478-1 ↗
29. 10.1021/acsaem.8b0112210.1021/acsaem.8b01122 ↗
30. 10.1002/adom.20180027610.1002/adom.201800276 ↗
31. 10.1039/C8EE01576G10.1039/C8EE01576G ↗
32. 10.1016/j.mtsust.2021.10009010.1016/j.mtsust.2021.100090 ↗
33. 10.1039/C9SC01184F10.1039/C9SC01184F ↗
34. 10.1038/srep0059110.1038/srep00591 ↗
35. 10.1038/srep0475610.1038/srep04756 ↗
36. 10.1002/cphc.20170091010.1002/cphc.201700910 ↗
37. 10.1002/solr.20190010410.1002/solr.201900104 ↗
38. 10.1039/D0EE02337J10.1039/D0EE02337J ↗
39. 10.1021/acsami.0c1996810.1021/acsami.0c19968 ↗
40. 10.1039/C8EE01500G10.1039/C8EE01500G ↗
41. 10.1002/adfm.20150424510.1002/adfm.201504245 ↗
42. Tress, W.; Marinova, N.; Inganäs, O.; Nazeeruddin, M. K.; Zakeeruddin, S. M.; Graetzel, M., The Role of the Hole-Transport Layer in Perovskite Solar Cells - Reducing Recombination and Increasing Absorption. In 2014 IEEE 40th Photovoltaic Specialist Conference (PVSC);June 8–13, 2014; IEEE, 2014; pp 1563–1566.10.1109/PVSC.2014.6925216 ↗
43. 10.1039/C8TA05234D10.1039/C8TA05234D ↗
44. 10.1016/j.nanoen.2017.02.02510.1016/j.nanoen.2017.02.025 ↗
45. 10.1038/nenergy.2015.110.1038/nenergy.2015.1 ↗
46. Tress W. · 2016 · 5310.1007/978-3-319-35114-8_3 ↗
47. 10.1002/aenm.20160013210.1002/aenm.201600132 ↗
48. 10.1021/jz500059v10.1021/jz500059v ↗
49. 10.1007/s10825-016-0850-110.1007/s10825-016-0850-1 ↗
50. 10.1016/j.solener.2019.12.01410.1016/j.solener.2019.12.014 ↗
51. 10.1039/C5RA18648J10.1039/C5RA18648J ↗
52. 10.1039/D0TA11564A10.1039/D0TA11564A ↗
53. 10.1002/admi.20170062310.1002/admi.201700623 ↗
54. 10.1021/cr050134110.1021/cr0501341 ↗
55. 10.1080/1364281860824317410.1080/13642818608243174 ↗
56. 10.1016/S0379-6779(98)80033-710.1016/S0379-6779(98)80033-7 ↗
57. 10.1038/2693610.1038/26936 ↗
58. 10.1002/masy.1998125011010.1002/masy.19981250110 ↗
59. 10.1002/aenm.20170251210.1002/aenm.201702512 ↗
60. 10.1038/srep0059110.1038/srep00591 ↗
61. 10.1063/1.242455210.1063/1.2424552 ↗
62. 10.1039/c4ee00168k10.1039/c4ee00168k ↗
63. 10.1039/C5TA05470B10.1039/C5TA05470B ↗
64. 10.1021/acsnano.5b0044710.1021/acsnano.5b00447 ↗
65. 10.1039/C5TA03443D10.1039/C5TA03443D ↗
66. 10.1016/j.cplett.2017.09.03110.1016/j.cplett.2017.09.031 ↗
67. 10.1021/acsami.9b2117710.1021/acsami.9b21177 ↗
68. 10.1021/acsenergylett.7b0058210.1021/acsenergylett.7b00582 ↗
69. 10.1039/C3CP53834F10.1039/C3CP53834F ↗
70. 10.1021/nn204296b10.1021/nn204296b ↗
71. 10.1063/1.152586610.1063/1.1525866 ↗
72. 10.1103/PhysRevApplied.9.04401710.1103/PhysRevApplied.9.044017 ↗
73. 10.1021/ja504539w10.1021/ja504539w ↗
74. 10.1039/D1EE02095A10.1039/D1EE02095A ↗
75. 10.1016/j.solmat.2016.03.02410.1016/j.solmat.2016.03.024 ↗
76. 10.1002/aenm.20140034510.1002/aenm.201400345 ↗
77. 10.1002/anie.20140533410.1002/anie.201405334 ↗
78. 10.1038/nphoton.2014.13410.1038/nphoton.2014.134 ↗
79. 10.1039/C4EE03773A10.1039/C4EE03773A ↗
80. 10.1021/ja502824c10.1021/ja502824c ↗
81. 10.1002/aenm.20190151910.1002/aenm.201901519 ↗
82. 10.1126/science.125476310.1126/science.1254763 ↗
83. 10.1021/ja207367t10.1021/ja207367t ↗
84. 10.1002/adma.20130094710.1002/adma.201300947 ↗
85. 10.1063/1.222206310.1063/1.2222063 ↗
86. 10.1021/ja805850q10.1021/ja805850q ↗
87. 10.1021/acs.nanolett.6b0215810.1021/acs.nanolett.6b02158 ↗
88. 10.1016/j.nanoen.2020.10448310.1016/j.nanoen.2020.104483 ↗
89. 10.1021/cm504022q10.1021/cm504022q ↗
90. 10.1002/admi.20160011710.1002/admi.201600117 ↗
91. 10.1021/acsami.5b0770310.1021/acsami.5b07703 ↗
92. 10.1021/nl302509q10.1021/nl302509q ↗
93. 10.1021/jp207968b10.1021/jp207968b ↗
94. 10.1039/c2cp44397j10.1039/c2cp44397j ↗
95. 10.1021/ja075704o10.1021/ja075704o ↗
96. 10.1038/nature1250910.1038/nature12509 ↗
97. 10.1016/j.jallcom.2020.15499110.1016/j.jallcom.2020.154991 ↗
98. 10.1002/admi.20160011710.1002/admi.201600117 ↗
99. 10.1039/D0TA12458C10.1039/D0TA12458C ↗
100. 10.1038/nenergy.2015.1610.1038/nenergy.2015.16 ↗