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SMALL METHODS

WILEY-V C H VERLAG GMBH

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4,643 papers
Sustainable Upcycling of Spent LiCoO 2 Toward High‐Stability NCM Cathode via Eutectic Molten Salt Synthesis

Mengdan Jiang, Chunxian Xing, Zhuoli Yang, Long Chen et al.

ABSTRACT Spent LiCoO 2 (S‐LCO) cathode materials from retired lithium‐ion batteries (LIBs) pose severe environmental threats and represent a noteworthy waste of strategic resources. The emerging regeneration/upcycling approach for S‐LCO mainly adopts solid‐state treatment, showing significant potential of short‐range, high‐efficient reactivation of S‐LCO materials. Yet it su…

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Development of PFAS Responsive Electrolyte‐Gated Field‐Effect Transistors Using Conjugated Polymer‐Single‐Walled Carbon Nanotube Complexes

Roozbeh Javad Kalbasi, Mokhamed Ranne, May Ourabi, Benoît H. Lessard et al.

ABSTRACT Conjugated polymers are effective dispersants of SWNTs which also impart their properties onto polymer‐SWNT complexes. By modifying the polymer sidechain, the properties of the complex can be fine‐tuned for targeted applications. Here, we introduced pillar[5]arenes containing pendant quaternary ammonium groups onto the polymer side chains using strain promoted azide‐al…

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Profiling Multiplexed Protein‐Specific Sialylation in Cancer Drug Resistance Using Proximity Ligation Sequencing

Ning Zhang, Gaoyu Song, Zhiyuan Peng, Kangjia Du et al.

ABSTRACT Aberrant glycosylation, particularly enhanced sialylation of membrane proteins, acts as a critical regulator of receptor signaling, immune evasion, and therapeutic resistance in cancer. However, systematic and multiplexed interrogation of protein‐specific sialylation in living cells remains technically challenging. Here, we report SATP‐seq, a next‐generation sequencing…

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Integrating Low‐Voltage Microfluidics With On‐Chip Electrospray Ionization for Miniaturized Protein Analysis

Noor Hidayat Abu Bakar, Hsiung‐Lin Tu

ABSTRACT Low‐input proteomics requires analytical strategies that can handle very small volumes while minimizing loss, dilution, and handling steps. Low‐voltage electrokinetic microfluidics offers a promising route to this goal by enabling controlled transport, separation, concentration, and droplet manipulation within compact chip‐based platforms. This review examines the inte…

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Electronic Locking of Labile Cobalt Spinel by Highly Dispersed Iridium for Stable Acidic Water Oxidation

Ying Lang, Ruoyao Zhong, Yuxiao Weng, Linfeng Lei et al.

ABSTRACT The widespread development of proton exchange membrane water electrolyzers (PEMWEs) is severely impeded by the scarcity of iridium‐based anodic catalysts. While non‐noble transition metal oxides (TMOs) (e.g., cobalt spinels) offer a cost‐effective alternative, they suffer rapid structural collapse in harsh acidic environments due to lattice oxygen over‐oxidation and su…

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Progress on Synergistic Enhancement of Perovskite Solar Cell Efficiency and Stability via Defect Engineering and Carrier Dynamics Optimization

Dingwei Wang, Weidan Gu, Qingshan Li, Bin Du et al.

ABSTRACT Perovskite solar cells (PSCs) exhibit excellent optoelectronic properties, including a high light absorption coefficient and superior carrier mobility. However, challenges remain in their power conversion efficiency and stability. Intrinsic defects and externally introduced defects exert a key impact on their optoelectronic properties. This paper systematically reviews…

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Engineering Co–O–Ru Motifs in RuO 2 Nanosheets via Asymmetric Spin Polarization for High‐Performance and Durable PEM Water Electrolysis

Zijie Wu, Hongwei Cao, Lu Ding, Tao Zhou et al.

ABSTRACT The intrinsic activity‐stability trade‐off of RuO 2 remains a fundamental bottleneck, impeding its long‐term viability in acidic oxygen evolution reaction (OER) and large‐scale proton exchange membrane water electrolyzer (PEMWE) deployment. While spin‐polarization modulation has emerged as a compelling paradigm for catalyst optimization, establishing rigorous atomic…

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Advanced Manufacturing Routes for Electrodes and Cells in All‐Solid‐State Batteries: From Powder to Power

Heejoo Park, Soyeon Kong, Jihyun Jang

ABSTRACT All‐solid‐state batteries (ASSBs) represent promising next‐generation energy storage systems with superior safety and energy density compared to conventional lithium‐ion batteries (LIBs). This review comprehensively examines advanced electrode and cell manufacturing processes that are critical to the commercialization of ASSBs. Electrode fabrication processes are categ…

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Regional Segregated Architecture Strategy for High‐Efficiency Microwave Absorption of Polyimide Foam

Nan Li, Zhuo‐Yang Li, Feng Zhang, Jun‐Feng Shi et al.

ABSTRACT Polyimide (PI) microwave absorption (MA) foam characterized by its superior electromagnetic protection performance and adjustable mechanical properties, is considered a quintessential structure‐function integrated material. Currently, the expressed low compressive strength (∼kPa) of PI MA foam matrix limits application as a direct load‐bearing component, despite potent…

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Controlled Grain Growth Deposition for Enhanced Bulk and Interfacial Defect Passivation in Vacuum‐Deposited FAPbI 3 Perovskite Solar Cells

Minji Jeong, Jihye Park, Giryun Kim, Siwon Yun et al.

ABSTRACT Vacuum deposition of perovskite thin films offers superior conformality and precise control over solution‐based methods. However, non‐uniform nucleation and island‐like growth produce columnar grains, voids, and trap states at the electron‐transport layer (ETL)/perovskite interface, causing non‐radiative recombination. In conventional co‐deposition, volatile formamidin…

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Suppressing Intrinsic Defects via Ag Doping Enables High‐Performance InSe Field‐Effect Transistors

Zhenhua Wang, Zheng Zhang, Hao Ji, Hengji Li et al.

ABSTRACT InSe is a highly promising material for the next‐generation nanoelectronics due to unique optoelectronic and electronic performance. However, the presence of intrinsic defects plays a detrimental role in InSe field‐effect transistors (FETs) and photodetectors, which causes carrier scattering and degrades performance. Herein, we demonstrated an efficient Ag doping strat…

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Durable, Binder‐Free MoO 3 /Fe 2 O 3 /MoS 2 Honeycomb Heterostructure for Light‐Enhanced Water Splitting at Industrial Current Density

Arvind Swami, Aash Mohammad, Milan Kumar, Debashis Panda

ABSTRACT Hydrogen production via alkaline water electrolysis is limited by sluggish oxygen evolution reaction (OER) kinetics, poor durability of electrocatalysts, and the energy‐intensive synthesis of these catalysts. Herein, we report ligand‐assisted, temporal decoupling strategy in solvothermal synthesis of FeMo bifunctional electrocatalysts with a unique MoO 3 /Fe 2 O …

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Recrystallization‐Driven Formation of Single‐Crystalline MoS 2 by Metal‐Organic Chemical Vapor Epitaxy

Iryna Kandybka, Pawan Kumar, Henry Medina Silva, Benjamin Groven et al.

ABSTRACT Single‐crystalline molybdenum disulfide (MoS 2 ) emerges as a leading n‐type channel material for high‐performance electronic devices in the angstrom era of computing. Chemical vapor epitaxy of single‐crystalline MoS 2 relies on sapphire template engineering to impose a preferred crystalline orientation. A challenge of these approaches is to control the within‐wa…

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How We Simulate Nanopores

Behzad Mehrafrooz, Xavier Mleziva, Meng Xu, Melika Shekari et al.

ABSTRACT Nanopore technology has revolutionized single‐molecule science by enabling ultrasensitive characterization of biomolecular structure and interactions via accessible, physics‐based tabletop measurements. In a typical experiment, the chemical structure of a biomolecule is determined by measuring a transient blockade of the nanopore ionic current produced by the nanopore …

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Large Language Model Guided Discovery of Hole Transport Layer Dopants for Efficient and Stable Perovskite Photovoltaics

Jiazheng Wang, Xinxin Xu, Qiang Lou, Hongye Liu et al.

ABSTRACT Achieving high efficiency and long‐term stability in n‐i‐p perovskite solar cells (PSCs) remains constrained by the hole transport layer (HTL) dopant chemistry. The most commonly used dopant for 2,2',7,7'‐tetrakis(N,N‐di‐4‐methoxyphenylamino)‐9,9'‐spirobifluorene (Spiro‐OMeTAD), typically based on lithium bis(trifluoromethanesulfonyl)imide, enables state‐of‐the‐art pow…

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Dynamic Phase Transition Driven Achievement of Ultra‐Broadband Microwave Absorption in FeCoNiCrMo High‐Entropy Alloys

Ning Zhu, Jianzhao Wang, Xiaolian Liu, Zhenhua Zhang et al.

ABSTRACT Although soft magnetic high‐entropy alloys (HEAs) offer the advantage of broadband absorption in microwave absorption materials, it remains challenging to simultaneously enhance their saturation magnetization (M s ) and coercivity (H c ). This trade‐off limits further improvements in both the permeability and effective absorption bandwidth (EAB). This work addres…

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Hydrothermal‐Assisted High‐Yield Production of Large‐Area Ti 3 C 2 T x MXene for High‐Performance Transparent Conductive and EMI‐Shielding Films

Yeongwon Kwak, Gang‐Young Kim, Wang‐Sang Lee, V. Vinay K. Doddapaneni et al.

ABSTRACT MXenes, a family of two‐dimensional transition metal carbides and nitrides, are promising for optoelectronic and shielding applications owing to their high electrical conductivity and tunable surface chemistry. However, their commercialization is hindered by poor oxidation stability, low‐yield synthesis, hydrofluoric acid‐based etching, and difficulty in producing larg…

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Dynamic Hydroxyl Replenishment to Stabilize Lattice Oxygen Via Polyhydroxy Metal Ions Mediation in Seawater Electrolysis

Lanke Luo, Shuo Wang, Yuxin Han, Zemin Sun et al.

ABSTRACT Seawater oxidation reaction (SOR) offers a sustainable route for hydrogen production, but imposes stringent requirements on catalysts. Under operating conditions, catalysts must maintain high oxygen evolution reaction (OER) activity, excellent selectivity, and resistance to chloride ion corrosion. Herein, to address the bottlenecks in catalytic activity and durability …

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Networked Solid Polymer Electrolyte Enabling 5C Fast Cycling and Enhanced Stability of Oriented LiCoO 2 All‐Solid‐State Thin Film Batteries

Yi‐Xiu Chen, Minh Le Nguyen, Pin‐Chuan Chao, Arijit Mitra et al.

ABSTRACT Polyethylene oxide (PEO)‐based solid polymer electrolytes (SPEs) have emerged as promising candidates for advancing the all‐solid‐state lithium metal batteries (ASSLMBs) market. However, conventional PEO‐based SPEs exhibit low room‐temperature (RT) ionic conductivity and limited oxidative stability (restricted to ∼4.2 V), which impedes their compatibility with high‐vol…

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A Micron‐Scale K 2 V 6 O 16 ·1.5H 2 O‐Based Aqueous Ink for Inkjet‐Printed Large‐Area Multicolor Electrochromic Displays

Hang Zhou, Xiaodan Guo, Zhijie Zheng, Chunjing Li et al.

ABSTRACT Inkjet printing offers a promising non‐contact route toward high‐throughput, large‐area manufacturing of functional films for next‐generation optoelectronic devices. However, the broader adoption in continuous production lines is hindered by the coffee‐ring effect that compromises film uniformity. Additionally, existing printable inks rely predominantly on nanoscale pa…

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