journal article·2021-11Open access

Structural Analysis of silica aerogels for the interlayer dielectric in semiconductor devices

YongJin Kim, SangHyuk Yoo, Hyung Gyu Lee, Yoonjin Won, Jimin Choi, Keonwook Kang

Ceramics International· Volume 47· Issue 21

Abstract

As semiconductor devices have become miniaturized and highly integrated, interconnection problems such as RC delays, power dissipation, and crosstalk appear. To alleviate these problems, materials with a low dielectric constant should be used for the interlayer dielectric in nanoscale semiconductor devices. Silica aerogel as a porous structure composed of silica and air can be used as the interlayer dielectric material to achieve a very low dielectric constant. However, the problem of its low stiffness needs to be resolved for the endurance required in planarization. The purpose of this study is to discover the geometric effect of the electrical and mechanical properties of silica aerogel. The effects of porosity, the distribution of pores, the number of pores on the dielectric constant, and elastic modulus were analyzed using FEM. The results suggest that the porosity of silica aerogel is the main parameter that determines the dielectric constant and it should be at least 0.76 to have a very low dielectric constant of 1.5. Additionally, while maintaining the porosity of 0.76, the silica aerogel needs to be designed in an ordered open pores structure (OOPS) containing 64 or more pores positioned in a simple cubic lattice point to endure in planarization, which requires an elastic modulus of 8 GPa to prevent delamination.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Aerogels and thermal insulation · Surface Modification and Superhydrophobicity · Silicone and Siloxane Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (29)

Show source-provided references
1. Transitioning semiconductor companies enabling smart environments and integrated ecosystems10.4236/ojbm.2018.62031 ↗
2. 2018
3. SiO2 aerogel film as a novel intermetal dielectric10.1063/1.365902 ↗
4. One step process of decomposition and polymerization to fabricate SiO2 hollow spheres/polyimide composite for foldable OLEDs10.1016/j.mseb.2016.11.001 ↗
5. Low-k dielectric materials10.1016/S1369-7021(04)00053-7 ↗
6. Nanometer-scale organization of ethylene oxide surfactants on graphite, hydrophilic silica, and hydrophobic silica10.1021/jp980266g ↗
7. In search of low-k dielectrics10.1126/science.286.5439.421 ↗
8. Air spacer for 10nm FinFET CMOS and beyond
9. Pinch off plasma CVD deposition process and material technology for nano-device air gap/spacer formation10.1149/2.0021811jss ↗
10. Manufacturable extremal low-dielectric, high-stiffness porous materials10.1063/1.1929854 ↗
11. Modulus-density scaling behaviour and framework architecture of nanoporous self-assembled silicas10.1038/nmat1913 ↗
12. Self-assembly and characterization of mesostructured silica films with a 3D arrangement of isolated spherical mesopores10.1002/adfm.200390005 ↗
13. Nanoporous ultralow dielectric constant organosilicates templated by triblock copolymers10.1021/cm010690l ↗
14. Low-pressure CMP for reliable porous low-k/Cu integration
15. Characterization of patterned low-k film delamination during CMP for the 32nm node Cu/ultra low-k (k=1.6-1.8) integration
16. Understanding CMP-induced delamination in ultra low-k/Cu integration
17. Pure-silica zeolite low-k dielectric thin films10.1002/1521-4095(200105)13:10<746::AID-ADMA746>3.0.CO;2-J ↗
18. Design and compressive behavior of controllable irregular porous scaffolds: based on voronoi-tessellation and for additive manufacturing10.1021/acsbiomaterials.7b00916 ↗
19. ANSYS, Inc. Ansys® Academic Research Electronics Desktop, Release 17.1, Help System, Electronics Desktop Guide.
20. 2019
21. Influence of substrates on the elastic reaction of films for the microindentation tests10.1016/0040-6090(95)08498-3 ↗
22. 2016
23. Microstructural characteristics and elastic modulus of porous solids10.1016/j.actamat.2015.02.014 ↗
24. LVI. On the influence of obstacles arranged in rectangular order upon the properties of a medium10.1080/14786449208620364 ↗
25. A general model of dielectric constant for porous materials
26. Effective design and simulation of surface-based lattice structures featuring volume fraction and cell type grading10.1016/j.matdes.2018.05.058 ↗
27. The manufacturability and compression properties of the Schwarz Diamond type Ti6Al4V cellular lattice fabricated by selective laser melting10.1007/s00170-019-04422-6 ↗
28. Influence of the structural orientation on the mechanical properties of selective laser melted Ti6Al4V open-porous scaffolds10.1016/j.matdes.2016.01.095 ↗
29. Thin aerogel films for optical, thermal, acoustic and electronic applications10.1016/0022-3093(95)00028-3 ↗