journal article·2012-09Open access

Grain size effect on the structural and dielectric properties of Pb0.85La0.15TiO3 ferroelectric ceramic compound

Alexandre Mesquita, Maria Inês Basso Bernardi, Claude Godart, Paulo Sergio Pizani, Alain Michalowicz, Valmor Roberto Mastelaro

Ceramics International· Volume 38· Issue 7

Abstract

Abstract This paper presents a study of the influence of particle size on the structural and dielectric properties of Pb 0.85 La 0.15 TiO 3 (PLT15) ferroelectric ceramic samples. The samples were prepared with average grain size of 1.69 ± 0.08 μm and 146 ± 8 nm using, respectively, conventional and spark plasma sintering techniques. A decrease in the tetragonality degree as the crystallite size decreased was explained by an internal stress caused by the existence of a large amount of grain boundaries. The local structure exhibited no significant modification and the dielectric measurements showed a diffuse phase transition and a reduction in the permittivity magnitude at T m as the average grain size decreased. The nanostructured ceramic sample prepared at a relatively lower temperature and sintering time presented a dielectric constant value of approximately 2000 at room temperature.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Multiferroics and related materials

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