journal article·2015-06

Influence of Eu doping on the magnetoelectric and dielectric properties of BiFeO3–Bi0.5Na0.5TiO3 ceramics

Gebru Zerihun, Shuai Huang, Gaoshang Gong, Songliu Yuan

Ceramics International· Volume 41· Issue 5
Publisher page

Abstract

Abstract Multiferroic 0.7Bi 1- x Eu x FeO 3 –0.3Bi 0.5 Na 0.5 TiO 3 ceramics with x =0, 0.025, 0.05 and 0.1 were prepared by using the sol–gel method. The effects of Eu doping on the magnetic, ferroelectric and dielectric properties of 0.7BiFeO 3 –0.3Bi 0.5 Na 0.5 TiO 3 ceramics were investigated. The X-ray diffraction confirmed that the structure of pure and Eu doped 0.7BiFeO 3 –0.3Bi 0.5 Na 0.5 TiO 3 ceramics are rhombohedral with space group R3m . Compared with the pure 0.7BiFeO 3 –0.3Bi 0.5 Na 0.5 TiO 3 , the magnetic properties of Eu doped samples were significantly enhanced due to structural distortion that results in the canting of spins. Ferroelectric measurements proved that Eu doping enhanced the polarization of the solid solutions by suppressing the oxygen vacancies. Improved coexistence of ferromagnetism and ferroelectricity were observed at room temperature with remnant magnetization M r =0.117 emu/g and remnant polarization P r =1.43 μC/cm 2 for x =0.05. The Eu doped samples confirmed the improvement of the dielectric properties.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Multiferroics and related materials · Ferroelectric and Piezoelectric Materials · Dielectric properties of ceramics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Electrical control of antiferromagnetic domains in multiferroic BiFeO3 films at room temperature10.1038/nmat1731 ↗
2. Thickness and frequency dependence of magnetoelectric effect for epitaxial La0.7Sr0.3MnO3/BaTiO3 bilayer10.1016/j.jallcom.2014.01.021 ↗
3. Spiral magnetic ordering in bismuth ferrite10.1088/0022-3719/15/23/020 ↗
4. Crystal structure refinement of Bi1-xNdxFeO3 multiferroic by the Rietveld method10.1016/j.ceramint.2012.01.046 ↗
5. Reaction pathways in the solid state synthesis of multiferroic BiFeO310.1016/j.jeurceramsoc.2011.03.018 ↗
6. Investigation on magnetic behavior of BiFeO3: spin glass view point10.5185/amlett.2013.fdm.82 ↗
7. Magnetic and electrical properties of single-phase multiferroic BiFeO310.1063/1.1881775 ↗
8. Room-temperature saturated ferroelectric polarization in BiFeO3 ceramics synthesized by rapid liquid phase sintering10.1063/1.1667612 ↗
9. Ferroelectricity in a pure BiFeO3 ceramic10.1063/1.126468 ↗
10. Structural, dielectric and magnetic properties of La0.8Bi0.2Fe1−xMnxO3 (0.0≤x≤0.4) multiferroics10.1063/1.3386527 ↗
11. Enhanced magnetoelectric properties in Bi0.95Ho0.05FeO3 polycrystalline ceramic10.1016/j.jallcom.2011.09.012 ↗
12. Ferroelectric and ferromagnetic properties of Gd-modified BiFeO310.1016/j.jmmm.2013.04.041 ↗
13. Structure and multiferroic properties of Eu-substituted BiFeO3 ceramics10.1007/s00339-012-7311-x ↗
14. A comparative study of structural, electrical and magnetic properties rare-earth (Dy and Nd)-modified BiFeO3
15. Effect of Dy-substitution on structural, electrical and magnetic properties of multiferroic BiFeO3 ceramics10.1016/j.ceramint.2013.12.148 ↗
16. Dielectric, ferroelectric and piezoelectric properties of BiFeO3–BaTiO3 Ceramics10.1111/jace.12475 ↗
17. Piezoelectric properties and temperature stabilities of Mn- and Cu-modified BiFeO3–BaTiO3 high temperature ceramics10.1016/j.jeurceramsoc.2012.11.019 ↗
18. Very high remnant polarization and phase-change electromechanical response of BiFeO3–PbTiO3 at the multiferroic morphotropic phase boundary10.1063/1.4764537 ↗
19. Exceptionally large piezoelectric strains in BiFeO3–(K0.5Bi0.5)TiO3–PbTiO3 ceramics10.1016/j.scriptamat.2012.11.029 ↗
20. Addition of small amounts of BiFeO3 to (Li, K, Na)(Nb,Ta)O3 lead-free ceramics: Influence on phase structure, microstructure and piezoelectric properties10.1016/j.jeurceramsoc.2012.05.019 ↗
21. Enhanced multiferroic properties and tunable magnetic behavior in multiferroic BiFeO3–Bi0.5Na0.5TiO3 solid solutions10.1016/j.mseb.2011.07.012 ↗
22. Current status and prospects of lead-free piezoelectric ceramics10.1016/j.jeurceramsoc.2005.03.125 ↗
23. Ferromagnetic, ferroelectric and fatigue behavior of (111)-oriented BiFeO3/(Bi0.5Na0.5)TiO3 lead free bilayered thin films10.1063/1.3127519 ↗
24. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
25. Role of oxygen vacancy and Fe–O–Fe bond angle in compositional, magnetic and dielectric relaxation on Eu-substituted BiFeO3 nanoparticles10.1039/C3DT52260A ↗
26. Enhanced photocatalytic activity and ferromagnetism in Gd doped BiFeO3 nanoparticles10.1021/jp104660a ↗
27. Enhanced multiferroic properties in Ti-doped Bi2Fe4O9 ceramics10.1063/1.3478705 ↗
28. Origin of enhanced magnetization in rare earth doped multiferroic bismuth ferrite10.1063/1.4865958 ↗
29. Enhanced electrical prop erties of rare-earth-substituted (Bi0.9RE0.1)(Fe0.975Cr0.025)O3 (RE=Nd, Gd, Eu) thin films10.3938/jkps.61.1404 ↗
30. Structural, dielectric, magnetic, magneto dielectric and impedance spectroscopic studies of multiferroic BiFeO3–BaTiO3 ceramics10.1016/j.mseb.2011.01.010 ↗
31. On the thermodynamic stability of BiFeO310.1021/cm802607p ↗
32. Properties of the solid solution (1−x)Na0.5Bi0.5TiO3–(x)BiFeO310.1016/j.jmmm.2009.02.014 ↗
33. Multiferroic properties of microwave sintered BaTiO3–SrFe12O19 composites10.1016/j.physb.2014.04.073 ↗
34. Dielectric behavior and ac conductivity in Aurivillius Bi4Ti3O12 doped by antiferromagnetic BiFeO310.1016/j.physleta.2012.01.012 ↗
35. Enhanced multiferroic properties of BiFeO3 ceramics by Ba and high-valence Nb co-doping10.1016/j.ssc.2012.09.005 ↗
36. Effect of Mn doping on multiferroic properties in Bi0.8Ba0.2FeO3 ceramics10.1016/j.ceramint.2013.11.029 ↗
37. Studies on electrical and dielectric properties of Ba1−xSrxTiO310.1016/j.matchemphys.2007.02.027 ↗