journal article·2019-01

The (1-x)Ba0.85Ca0.15Zr0.08Ti0.92 —xGe lead-free ceramics with high piezoelectric activity and ultrahigh dielectric constant

Fangfang Zeng, Qibin Liu, Shiqiang Peng, Yuanyu Wang, Enpei Cai, An Xue, Shunlong Zhou

Ceramics International· Volume 45· Issue 1
Publisher page

Abstract

Abstract In the work, the (1-x)Ba0.85Ca0.15Zr0.08Ti0.92—xGe (abbreviated as BCZT-xGe) lead-free piezoelectric ceramics were successfully prepared by conventional solid-state reaction method. The authors studied the effects of GeO2 on phase transition behavior and piezoelectric, ferroelectric and dielectric properties of BCZT-xGe ceramics. The results showed that piezoelectric activity of ceramics were dramatically enhanced by doping GeO2, and the piezoelectric coefficient (d33) reached the maximum of 348 pC/N at x = 0.03 wt%, which is close to orthorhombic-tetragonal (O-T) phase boundary. Besides, ultrahigh dielectric constant (er = 40000) was obtained at x = 0.03 wt%. When x = 0.03 wt%, the remnant polarization (Pr) and coercive field (Ec) were 3.39 μC/cm2 and 0.47 kV/mm, respectively. Consequently, the properties were optimized at x = 0.03 wt%.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (19)

Show source-provided references
1. High piezoelectric coefficient of Pr2O3-doped Ba0.85Ca0.15Ti0.90Zr0.10O3 ceramics10.1016/j.ceramint.2012.05.008 ↗
2. Recent development in lead-free perovskite piezoelectric bulk materials10.1016/j.pmatsci.2018.06.002 ↗
3. Large piezoelectric effect in Pb-free ceramics10.1103/PhysRevLett.103.257602 ↗
4. Giant piezoelectricity and high curie temperature in nanostructured alkali niobate lead-free piezoceramics through phase coexistence10.1021/jacs.6b09024 ↗
5. High piezoelectric d33 coefficient in (Ba1−xCax)(Ti0.98Zr0.02)O3 lead-free ceramics with relative high Curie temperature10.1016/j.matlet.2010.07.042 ↗
6. Phase transition characteristics and associated piezoelectricity of potassium-sodium niobate lead-free ceramics10.1039/C5DT01779C ↗
7. Composition and poling condition-induced electrical behavior of (Ba0.85Ca0.15)(Ti1−xZrx)O3 lead-free piezoelectric ceramics10.1016/j.jeurceramsoc.2011.11.003 ↗
8. Ultrahigh piezoelectricity in ferroelectric ceramics by design10.1038/s41563-018-0034-4 ↗
9. Effects of sintering temperature and poling conditions on the electrical properties of Bi0.50(Na0.70K0.20Li0.10)0.50TiO3 piezoelectric ceramics10.1016/j.jallcom.2012.02.067 ↗
10. Sintering temperature-induced electrical properties of (Ba0.90Ca0.10)(Ti0.85Zr0.15)O3 lead-free ceramics10.1016/j.materresbull.2012.01.032 ↗
11. Effect of dwell time during sintering on piezoelectric properties of (Ba0.85Ca0.15)(Ti0.90Zr0.10)O3 lead-free ceramics10.1016/j.jallcom.2011.08.024 ↗
12. Suppression of Ti3+ generation in Ba3.75Nd9.5Ti17.5M0.5O54 (M = Cu, Cr, Al, Mn) ceramics10.1016/j.ceramint.2018.07.091 ↗
13. Phase transition and improved electrical performance of Ba0.85Ca0.15Zr0.1Ti0.9O3 –Ca0.28Ba0.72Nb2O6 ceramics with high Curie temperature10.1016/j.matdes.2015.10.014 ↗
14. Potassium-sodium niobate lead-free piezoelectric materials: past, present, and future of phase boundaries10.1021/cr5006809 ↗
15. Enhanced electromechanical properties in <00l>-textured (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3 lead-free piezoceramics10.1016/j.ceramint.2015.10.139 ↗
16. Improved piezoelectric property and bright upconversion luminescence in Er doped (Ba0.99Ca0.01)(Ti0.98Zr0.02)O3 ceramics10.1016/j.jallcom.2013.08.103 ↗
17. High piezoelectric coefficient and temperature stability of Ga2O3-doped (Ba0.99Ca0.01)(Zr0.02Ti0.98)O3 lead-free ceramics by low-temperature sintering10.1016/j.jallcom.2013.07.131 ↗
18. Lead-free piezoelectric ceramics based on (1−x)BNKLLT–xBCTZ binary solid solutions synthesized by the solid-state combustion technique10.1007/s10853-016-9737-6 ↗
19. Enhanced dielectric properties in Ba0.85Ca0.15Zr0.10Ti0.90O3/La0.67Ca0.33MnO3 laminated composite10.1016/j.scriptamat.2017.09.044 ↗