journal article·2024-04Open access

One-step synthesis of single-crystal Si3N4 nanowires-amorphous SiO2 beads nanochains by chemical vapor deposition

Fen Yue, Jiuyi Zhu, Yuqi Geng, Maoqiao Xiang, Qingshan Zhu

Ceramics International· Volume 50· Issue 7

Abstract

One-dimensional (1D) nanochain heterojunctions have attracted wide attention due to their unique optical and electrical properties, while efficient and controllable synthesis of nanochains is still difficult. Herein, Si 3 N 4 /SiO 2 nanochain heterojunctions (Si 3 N 4 single-crystal nanowires and amorphous SiO 2 beads) were successfully synthesized by a one-step chemical vapor deposition (CVD) process without using any templates and catalysts. A two-stage growth mode was proposed to explain the formation mechanism of the special nanochain. We found that carbon vapor induced the formation of Si 3 N 4 nanowires and suppressed the formation of Si 2 N 2 O. The Si 3 N 4 /SiO 2 nanochains can only be synthesized within a suitable concentration range of carbon vapor. The as-synthesized fascinating nanochain exhibits an extra strong emission at about 3.02 eV, showing great promise for optoelectronic nanodevices .
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Research context

OpenAlex topics: Nanowire Synthesis and Applications · Silicon Nanostructures and Photoluminescence · Photonic Crystals and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Design strategy of phase and microstructure of Si3N4 ceramics with simultaneously high hardness and toughness10.26599/JAC.2023.9220671 ↗
2. Plastic deformation in silicon nitride ceramics via bond switching at coherent interfaces10.1126/science.abq7490 ↗
3. Silicon nitride for high-temperature applications10.1111/j.1551-2916.2010.03839.x ↗
4. Development of silicon nitride-based ceramic radomes - a review10.1111/ijac.12305 ↗
5. Si3N4 whiskers modified with titanium as stable Pt electrocatalyst supports for methanol oxidation and oxygen reduction10.1039/C4TA03818E ↗
6. Facile synthesis of Si3N4 nanowires with enhanced photocatalytic application10.1016/j.matlet.2017.10.045 ↗
7. Fe(NO3)3-assisted large-scale synthesis of Si3N4 nanobelts from quartz and graphite by carbothermal reduction-nitridation and their photoluminescence properties10.1038/srep08998 ↗
8. Recent progress in synthesis, growth mechanisms, properties, and applications of silicon nitride nanowires10.1016/j.ceramint.2021.02.139 ↗
9. Anisotropic, biomorphic cellular Si3N4 ceramics with directional well-aligned nanowhisker arrays based on wood-mimetic architectures10.1007/s40145-021-0555-1 ↗
10. All Si3N4 nanowires membrane based high-performance flexible solid-state asymmetric supercapacitor10.1002/smll.202008056 ↗
11. Aligned ultra-long single-crystalline α-Si3N4 nanowires10.1088/0957-4484/19/10/105602 ↗
12. Synthesis and properties of SiC/SiO2 nanochain heterojunctions by microwave method, cryst10.1021/cg800845h ↗
13. Photoluminescence properties of SiC/SiO2 heterojunctions obtained by TiO2-assisted chemical vapor deposition10.1016/j.ceramint.2018.03.152 ↗
14. Synthesis of photoluminescent SiC-SiOx nanowires using coal tar pitch as carbon source10.1016/j.ceramint.2020.07.207 ↗
15. Synthesis of silicon nitride nanowires directly from the silicon substrates
16. Formation mechanism of Si3N4 nanowires via carbothermal reduction of carbonaceous silica xerogels10.1021/jp0619282 ↗
17. Morphology control and blue luminescent performance of one dimensional Si3N4 via Nano-SiO2 assisted pyrolysis of polyvinylsilazane10.1016/j.ceramint.2023.03.160 ↗
18. Simultaneous synthesis of β-Si 3 N 4 nanofibers and pea-pods and hand-fan like Si 2 N 2 O nanostructures by the CVD method10.1016/j.matlet.2016.04.028 ↗
19. Metal catalysis-free, direction-controlled planar growth of single-crystalline alpha-Si3N4 nanowires on Si(100) substrate10.1088/0957-4484/17/15/064 ↗
20. Preparation of Si3N4 from carbothermal reduction of SiO employing the CRTA method10.4028/www.scientific.net/MSF.383.25 ↗
21. One-step molten-salt-mediated preparation and luminescent properties of ultra-long SiC/SiO2 core–shell nanowires10.1016/j.ceramint.2015.10.015 ↗
22. Enhancing photoluminescence properties of SiC/SiO2 coaxial nanocables by making oxygen vacancies10.1039/C6DT02049F ↗
23. Novel synthesis of SiC/SiO2 nanochain heterojunctions from agricultural waste10.1016/j.ceramint.2022.01.200 ↗
24. Synthesis and visible-light photocatalytic activity of SiC/SiO2 nanochain heterojunctions10.1016/j.matlet.2014.02.039 ↗
25. Visible photoluminescence from photoinduced molecular species in nanometer-sized oxides: crystalline Al2O3 and amorphous SiO2 nanoparticles10.1021/jp303359v ↗
26. Vapor pressure and evaporation coefficient of silicon monoxide over a mixture of silicon and silica10.1021/je200693d ↗
27. Seed particle formation for silicate dust condensation by SiO nucleation10.1051/0004-6361/201321807 ↗
28. Synthesis of ultralong Si3N4 nanowires by a simple thermal evaporation method10.1007/s12598-013-0050-0 ↗
29. Direct synthesis of α-silicon nitride nanowires from silicon monoxide on alumina10.5772/61661 ↗
30. High-temperature plateau–Rayleigh growth of beaded SiC/SiO2 nanochain heterostructures10.1021/acs.cgd.8b00057 ↗
31. Electronic structure of silicon nitride10.1080/01418639108224430 ↗
32. Correlation between the photoluminescence and chemical bonding in silicon nitride nanowires deposited by chemical vapour deposition10.1016/j.jallcom.2015.12.261 ↗
33. Catalyst-assisted synthesis and growth mechanism of ultra-long single crystal α-Si3N4 nanobelts with strong violet-blue luminescent properties10.1039/c2ce26010g ↗