journal article·2020-12

Structural, magnetic and cryogenic magneto-caloric properties in RE2FeCrO6 (RE = Er and Tm) compounds

Zhongqi Dong, Zhenjie Wang, Suhua Yin

Ceramics International· Volume 46· Issue 17
Publisher page

Abstract

Abstract In this work, polycrystalline Er2FeCrO6 (EFCO) and Tm2FeCrO6 (TFCO) oxides were fabricated via conventional sol-gel method, and studied with respect of crystal structure together with cryogenic magnetic and magneto-caloric properties. Both oxides are confirmed to exhibit B-site disordered hexagonal perovskite-type crystal structure. Two magnetic transitions around 11.7 and 5.7 K for EFCO, whereas only one transition around 10.5 K for TFCO, have been observed. Both oxides exhibit considerable cryogenic reversible magneto-caloric effects. The values of magnetic entropy change peak and relative cooling power (refrigerant capacity) with 0–5 T magnetic field change reach 11.95 J/kg-K and 215.8 (169.8) J/kg for EFCO, and 4.78 J/kg-K and 123.6 (97.8) J/kg for TFCO, respectively, indicating the present Er2FeCrO6 oxide is also considerable for cryogenic magnetic cooling application.
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Research context

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Thermal Expansion and Ionic Conductivity · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Advanced materials for magnetic cooling: fundamentals and practical aspects10.1063/1.4983612 ↗
2. Recent progresses in exploring the rare earth based intermetallic compounds for cryogenic magnetic refrigeration10.1016/j.jallcom.2020.153810 ↗
3. Magnetocaloric effect: from materials research to refrigeration devices10.1016/j.pmatsci.2017.10.005 ↗
4. Review of the structural, magnetic and magnetocaloric properties in ternary rare earth RE2T2X type intermetallic compounds10.1016/j.jallcom.2019.02.175 ↗
5. Review of magnetic properties and magnetocaloric effect in the intermetallic compounds of rare earth with low boiling point metals
6. Structural and cryogenic magnetic properties in AGd(MoO4)2 (A =Li, Na and K) compounds10.1016/j.ceramint.2019.07.174 ↗
7. Magnetic properties and magneto-caloric performances in RECo2B2C (RE = Gd, Tb and Dy) compounds10.1016/j.jallcom.2019.152780 ↗
8. Dielectric and magnetocaloric study of TmCrO310.1016/j.jallcom.2019.06.359 ↗
9. Achievement of a table-like magnetocaloric effect in the dual-phase ErZn2/ErZn composite10.1080/21663831.2017.1393778 ↗
10. Magnetocaloric effect and refrigeration performance in RE60Co20Ni20 (RE=Ho and Er) amorphous ribbons10.1016/j.jmmm.2019.166179 ↗
11. Giant reversible magnetocaloric effect in ErMn2Si2 compound with a second order magnetic phase transition10.1063/1.4704155 ↗
12. Magnetic structures and magnetocaloric effect in RVO4 (R=Gd, Nd)10.1103/PhysRevB.97.214401 ↗
13. Thermal and magnetic effects in quasi-binary Tb1-xDyxNi2 (x=0.25, 0.5, 0.75) intermetallics10.1016/j.actamat.2019.04.056 ↗
14. Two successive magnetic transitions induced large refrigerant capacity in HoPdIn compound10.1063/1.4834815 ↗
15. Microstructure and cryogenic magnetic properties in amorphousized RE57Cu25Al18 (RE = Ho and Tm) ribbons10.1016/j.jallcom.2018.08.210 ↗
16. Oxide perovskites, double perovskites and derivatives for electrocatalysis, photocatalysis, and photovoltaics10.1039/C8EE01574K ↗
17. The external and internal influences on the tuning of the properties of perovskites: an overview10.1016/j.ceramint.2018.11.102 ↗
18. Structural, magnetic and magnetocaloric properties in R2CoMnO6 (R = Dy, Ho, and Er)10.1016/j.ceramint.2017.08.158 ↗
19. Multiple magnetic phase transitions and magnetocaloric effect in double perovskites R2NiMnO6 (R = Dy, Ho, and Er)10.1016/j.jallcom.2017.08.073 ↗
20. Observation of ferroelectricity and magnetoelectric coupling in Mn-doped orthochromite DyCr0.5Mn0.5O310.1016/j.jallcom.2015.10.030 ↗
21. Cryogenic magnetic properties and magnetocaloric performance in double perovskite Pr2NiMnO6 and Pr2CoMnO6 compounds10.1016/j.ceramint.2018.08.075 ↗
22. Crystal structure, magnetic properties, and magnetocaloric effect in B-site disordered RE2CrMnO6 (R =Ho and Er) perovskites10.1016/j.ceramint.2020.01.238 ↗
23. Structural, magnetic and magnetocaloric properties in perovskite RE2FeCoO6 (RE = Er and Gd) compounds10.1016/j.ceramint.2019.09.077 ↗
24. Magnetic properties and excellent cryogenic magnetocaloric performances in B-site ordered RE2ZnMnO6 (RE = Gd, Dy and Ho) perovskites10.1016/j.actamat.2020.05.036 ↗
25. Magnetic properties and magnetocaloric effect in TmZnAl and TmAgAl compounds10.1016/j.jallcom.2015.10.026 ↗
26. Giant low field magnetocaloric effect and field-induced metamagnetic transition in TmZn10.1063/1.4932058 ↗
27. Magnetic properties and large magnetic entropy change in rare earth-rich cadmium compounds of RE4CoCd (RE = Tm and Ho)10.1016/j.intermet.2017.10.016 ↗
28. On a generalised approach to first and second order magnetic transitions10.1016/0031-9163(64)91158-8 ↗
29. Reversible table-like magnetocaloric effect in Eu4PdMg over a very large temperature span
30. Enhancement in magnetocaloric properties of holmium chromite by gadolinium substitution10.1063/1.4959253 ↗
31. Magnetic and magnetocaloric properties of iron substituted holmium chromite and dysprosium chromite10.1039/C5RA24323H ↗
32. Structure and cryogenic magnetic properties in Ho2BaCuO5 cuprate10.1016/j.ceramint.2017.10.143 ↗