journal article·2021-10

Ferroelectric K0.5Na0.5NbO3 catalysts for dye wastewater degradation

Mengmeng Lun, Xunsheng Zhou, Shanshan Hu, Ying Hong, Baolong Wang, Aihua Yao, Wei Li, Benli Chu, Qinyu He, Jun Cheng, Yinzhen Wang

Ceramics International· Volume 47· Issue 20
Publisher page

Abstract

Abstract K0.5Na0.5NbO3 (KNN) particles were prepared by a solid–state method. X–ray diffraction, scanning electron microscopy, UV–visible spectrophotometry, and electrochemical impedance spectroscopy were used to study the structure, morphology, and properties of the samples. The obtained KNN is a ferroelectric material with orthorhombic perovskite structure at room temperature. The KNN particles can be used as piezo/photo–bicatalysts for degrading organic pollutants by utilizing vibrational and solar energy; the catalytic activity of the particles can be significantly improved owing to their polarization under an applied electric field. Poled KNN particles show a bicatalytic degradation ratio of rhodamine B (RhB) dye reaching 92% after 60 min. The results indicate that the KNN particles can be applied as attractive ferroelectric catalysts for organic pollutant degradation.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (44)

Show source-provided references
1. Kinetic analysis of isothermal solid state process for synthesized potassium sodium niobate piezoelectric ceramics
2. Review of chemical modification on potassium sodium niobate lead-free piezoelectrics10.1039/C9TC00476A ↗
3. Review of high temperature piezoelectric materials, devices, and applications10.7498/aps.67.20181091 ↗
4. Review of the mechanical and fracture behavior of perovskite lead-free ferroelectrics for actuator applications10.1088/1361-665X/aa590c ↗
5. Effect of deposition temperature on orientation and electrical properties of (K0.5Na0.5)NbO3 thin films by pulsed laser deposition10.1016/j.apsusc.2011.10.116 ↗
6. Thermal and X‐ray diffraction studies of the NaNbO3–KNbO3 system10.1063/1.1655833 ↗
7. Micro-stereolithography of KNN-based lead-free piezoceramics10.1016/j.ceramint.2018.11.185 ↗
8. Alkaline-earth doping in (K,Na)NbO3 based piezoceramics10.1016/j.jeurceramsoc.2005.03.127 ↗
9. Effect of sintering time on structure and properties in CuO-doping KNN-LS-BF piezoelectric ceramics10.1007/s11595-019-2052-8 ↗
10. High Q(m) values and humidity effect on the electrical properties of (K, Na)NbO3 lead-free piezoceramics doped with B2O3-CuO mixed oxides10.1111/jace.14586 ↗
11. Dual-enhancement of ferro-/piezoelectric and photoluminescent performance in Pr3+ doped (K0.5Na0.5)NbO3 lead-free ceramics10.1063/1.4891959 ↗
12. Ferroelectric photocurrent effect in polycrystalline lead-free (K0.5Na0.5)(Mn0.005Nb0.995)O3 thin film10.1111/j.1551-2916.2012.05430.x ↗
13. Pyro-catalytic hydrogen evolution by Ba0.7Sr0.3TiO3 nanoparticles: harvesting cold–hot alternation energy near room-temperature10.1039/C8EE01016A ↗
14. Fluorinated 2D lead iodide perovskite ferroelectrics10.1002/adma.201901843 ↗
15. Water flow drived piezo-photocatalytic flexible films: Bi-piezoelectric integration of ZnO nanorods and PVDF10.1016/j.apsusc.2020.146119 ↗
16. Enhanced pyroelectric catalysis of BaTiO3 nanowires for utilizing waste heat in pollution treatment10.1021/acsami.8b11158 ↗
17. Synthesis of high efficient and stable plasmonic photocatalyst Ag/AgNbO3 with specific exposed crystal-facets and intimate heterogeneous interface via combustion route10.1016/j.apsusc.2019.05.173 ↗
18. Photothermally enabled pyro-catalysis of a BaTiO3 nanoparticle composite membrane at the liquid/air interface10.1021/acsami.8b03411 ↗
19. Insights into the role of ferroelectric polarization in piezocatalysis of nanocrystalline BaTiO310.1021/acsami.8b01991 ↗
20. Effect of ferroelectricity on solar-light-driven photocatalytic activity of BaTiO3—influence on the carrier separation and stern layer formation10.1021/cm402092f ↗
21. Effective enhancement of piezocatalytic activity of BaTiO3 nanowires under ultrasonic vibration10.1016/j.nanoen.2017.12.034 ↗
22. Strong pyro-catalysis of pyroelectric BiFeO3 nanoparticles under a room-temperature cold-hot alternation10.1039/C6NR00972G ↗
23. Insights into the structure-photoreactivity relationships in well-defined perovskite ferroelectric KNbO3 nanowires10.1039/C5SC00766F ↗
24. Enhanced photocatalytic activity on polarized ferroelectric KNbO310.1039/C6RA23344A ↗
25. Enhanced photocatalysis activity of ferroelectric KNbO3 nanofibers compared with antiferroelectric NaNbO3 nanofibers synthesized by electrospinning10.1039/C5RA13680F ↗
26. Coupling of piezoelectric, semiconducting and photoexcitation properties in NaNbO3 nanostructures for controlling electrical transport: realizing an efficient piezo-photoanode and piezo-photocatalyst10.1016/j.nanoen.2017.05.029 ↗
27. Visible light driven photocatalytic activity of palladium nanoparticles assisted potassium niobate microrods10.1016/j.apsusc.2019.143737 ↗
28. Lead-free sodium niobate nanowires with strong piezo-catalysis for dye wastewater degradation10.1016/j.ceramint.2019.03.045 ↗
29. Enhanced piezoelectric performance and thermal stability of alkali niobate-based ceramics10.1016/j.ceramint.2018.10.141 ↗
30. Ultrasonic vibration driven piezocatalytic activity of lead-free K0.5Na0.5NbO3 materials10.1016/j.ceramint.2019.07.271 ↗
31. Measurement of temperature in sonoplasma10.1143/JJAP.43.2833 ↗
32. A powerful bursting radio source towards the Galactic Centre10.1038/nature03400 ↗
33. High-efficiency and mechano-/photo- bi-catalysis of piezoelectric-ZnO@ photoelectric-TiO2 core-shell nanofibers for dye decomposition10.1016/j.chemosphere.2017.05.130 ↗
34. Alternative methods of microorganism disruption for agricultural applications10.1016/j.apenergy.2013.08.085 ↗
35. Structural, optical and photoluminescence properties of K0.5Na0.5NbO3 ceramics synthesized by sol-gel reaction method10.1007/s10971-018-4791-y ↗
36. p-Type/n-type behaviour and functional properties of KxNa(1-x)NbO3 (0.49≤x≤0.51) sintered in air and N210.1016/j.jeurceramsoc.2018.03.013 ↗
37. Control of the polarization of ferroelectric capacitors by the concurrent action of light and adsorbates10.1021/acsami.8b05751 ↗
38. Ferroelectric spontaneous polarization steering charge carriers migration for promoting photocatalysis and molecular oxygen activation10.1016/j.jcis.2017.09.005 ↗
39. A ferroelectric photocatalyst for enhancing hydrogen evolution: polarized particulate suspension10.1039/C4CP01267D ↗
40. Enhanced broad band photodetection through piezo-phototronic effect in CdSe/ZnTe core/shell nanowire array10.1002/aelm.201400050 ↗
41. Enhancing the visible light photocatalytic performance of ternary CdS–(graphene–Pd) nanocomposites via a facile interfacial mediator and co-catalyst strategy10.1039/C4TA04151H ↗
42. The role of polarization in photocatalysis10.1002/anie.201901361 ↗
43. Detection of active oxidative species in TiO2 photocatalysis using the fluorescence technique10.1016/S1388-2481(00)00006-0 ↗
44. Pyroelectrically induced pyro-electro-chemical catalytic activity of BaTiO3 nanofibers under room-temperature cold–hot cycle excitations10.3390/met7040122 ↗