Effect of Zr4+ content on the TC range and dielectric and ferroelectric properties of BaZrxTi1−xO3 ceramics prepared by microwave sintering

Abstract Single phase and dense BaZrxTi1−xO3 (BZT) ceramics (x=0.05, 0.1, 0.15, 0.2, 0.25) were obtained by microwave sintering and the powders of these ceramics were synthesized by conventional hydrothermal method. The microstructural, dielectric and ferroelectric properties of BaZrxTi1−xO3 ceramics sintered at 1300oC were investigated. The XRD analysis revealed that the synthesized compound was formed with no second phase. As x was increased from 0.05 to 0.25, the average grain size was observed on the SEM micrographs to decrease from ~6 μm to ~3 μm. The dielectric constant as a function of temperature showed a decrease in Curie temperature (TC) with an increasing x, while the maximum value of dielectric loss occurred (tan δ) at x=0.1. A ferroelectric-relaxor crossover was observed to take place with increasing x by using the modified Curie–Weiss law. The remnant polarization (Pr) decreased from 9.45 to 4.4 C/cm2 with an increasing x, while the maximum value of Pr=11.84 also occurred at x=0.1. The breadth of TC range increased rapidly when x